2-Vinylanthraquinone

Base Information

• Chemical Name: 2-Vinylanthraquinone
• CAS No.: 13388-33-5
• Molecular Formula: C16H10O2
• Molecular Weight: 234.254
• Mol file: 13388-33-5.mol

Synonyms:poly(2-vinylanthraquinone);2-vinylanthraquinone;2-vinyl-anthraquinone;2-vinyl-9,10-anthraquinone;poly(2-vinyl-anthraquinone);2-Vinyl-anthrachinon;2-Vinylanthrachinon;

Chemical Property of 2-Vinylanthraquinone

Chemical Property:

• Melting Point: 177°C(lit.)
• Boiling Point: 429.8±35.0 °C(Predicted)
• PSA: 34.14000
• Density: 1.266±0.06 g/cm3(Predicted)
• LogP: 3.10500
• Solubility.: soluble in Toluene

Purity/Quality:

97% ^*data from raw suppliers

2-Vinylanthraquinone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Vinylanthraquinone

There total 15 articles about 2-Vinylanthraquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2,4,6,8-tetramethyl-2,4,6,8-tetravinyl-cyclotetrasiloxane (2554-06-5) + 2-bromoanthracene-9,10-dione (572-83-8) → 2-vinylanthracene-9,10-dione (13388-33-5)

Guidance literature:

With tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium⁽⁰⁾; johnphos; In tetrahydrofuran; at 80 ℃; for 8h;

DOI:10.1039/c4ta01138d

Reference yield: 80.0%

2,4,6,8-tetramethyl-2,4,6,8-tetravinyl-cyclotetrasiloxane (2554-06-5) + 2-iodo-anthraquinone (10566-32-2) → 2-vinylanthracene-9,10-dione (13388-33-5)

Guidance literature:

With tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium⁽⁰⁾; johnphos; In tetrahydrofuran; at 80 ℃; for 8h; Inert atmosphere;

DOI:10.1002/pola.27716

Reference yield: 71.0%

2-iodo-anthraquinone (10566-32-2) + tri-tert-butyl(ethenyl)stannane (45152-58-7) → 2-vinylanthracene-9,10-dione (13388-33-5)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; for 20h; Heating;

DOI:10.1021/jo049741z

upstream raw materials:

3-(9,10-dioxo-9,10-dihydro-[2]anthryl)-acrylic acid

2-ethylanthraquinone

2-(1-hydroxyethyl)-9,10-anthraquinone

1-(9,10-dioxo-9,10-dihydroanthracen-2-yl)ethyl acetate

Downstream raw materials:

2-vinyl-9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene

2-vinyl-11,11,12,12-tetracyanoanthraquinodimethane