3-Phenanthrenecarboxylic acid ethyl ester

Base Information

• Chemical Name: 3-Phenanthrenecarboxylic acid ethyl ester
• CAS No.: 93321-42-7
• Molecular Formula: C₁₇H₁₄O₂
• Molecular Weight: 250.297
• Hs Code.: 2916399090
• Mol file: 93321-42-7.mol

Synonyms:3-Ethoxycarbonyl-phenanthren;Phenanthren-carbonsaeure-(3)-ethylester;phenanthrene-3-carboxylic acid ethyl ester;Phenanthren-3-carbonsaeure-aethylester;

Chemical Property of 3-Phenanthrenecarboxylic acid ethyl ester

Chemical Property:

• Vapor Pressure: 3.92E-07mmHg at 25°C
• Boiling Point: 416.1°Cat760mmHg
• Flash Point: 194.2°C
• PSA: 26.30000
• Density: 1.18g/cm³
• LogP: 4.16970
• Storage Temp.: 2-8°C

Purity/Quality:

Ethylphenanthrene-3-carboxylate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Phenanthrenecarboxylic acid ethyl ester

There total 3 articles about 3-Phenanthrenecarboxylic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

4-iodobenzoic acid ethyl ester (51934-41-9) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) + 2-bromobenzoic-acid (88-65-3) → ethyl phenanthrene-3-carboxylate (93321-42-7)

Guidance literature:

With palladium diacetate; caesium carbonate; tricyclohexylphosphine; In 1,4-dioxane; at 130 ℃; for 18h; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1002/anie.201703551

Reference yield:

ethanol (64-17-5) → ethyl phenanthrene-3-carboxylate (93321-42-7)

Guidance literature:

With sulfuric acid;

DOI:10.3758/BF03194964

Reference yield:

→ ethyl phenanthrene-3-carboxylate (93321-42-7)

Guidance literature:

3-Carboxy-phenanthren, A., HCl;

DOI:10.1021/ja00895a013

upstream raw materials:

ethanol

4-iodobenzoic acid ethyl ester

bicyclo[2.2.1]hepta-2,5-diene

2-bromobenzoic-acid