pentaammineaquaruthenium

Base Information

• Chemical Name: pentaammineaquaruthenium
• CAS No.: 21393-88-4
• Molecular Formula: H₁₇N₅ORu
• Molecular Weight: 204.238
• Mol file: 21393-88-4.mol

Synonyms:pentaammineaquaruthenium

Chemical Property of pentaammineaquaruthenium

Chemical Property:

• PSA: 150.33000
• LogP: 0.37170

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of pentaammineaquaruthenium

There total 3 articles about pentaammineaquaruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

[Ru(NH3)5(NHC(O)-bz-2-CN)](2+) (861853-08-9) → aquapentaammineruthenium(II)(2+) (21393-88-4) + [Ru(NH3)5(NC-bz-2-NH2C(O))](2+) (861853-10-3,861853-09-0)

Guidance literature:

In water; byproducts: 1,2-cyanobenzamide; Electrolysis; electrolysis (-500 mV vs Ag/AgCl) in 1 M CH3CO2H/CH3CO2(1-), pH 4.65); UV-Vis spectroscopy;

DOI:10.1016/j.ica.2004.09.008

Reference yield:

Ru(2+)*5NH3=Ru(NH3)5(2+) → hexaammineruthenium(III) (18943-33-4) + pentaammine ruthenium(III) chloride (21560-19-0) + aquapentaammineruthenium(III) (25590-52-7) + {Ru(NH3)5(OH)}(2+) (21393-88-4)

Guidance literature:

With hydrogen cation; sodium chloride; In water; byproducts: Co(2+), NH4(1+), I(1-); oxidation with (CoI(NH3)5)(2+) in NaCl soln. at pH <5; formation of a mixt. of (RuCl(NH3)5)(2+), (RuH2O(NH3)5)(3+), (RuOH(NH3)5)(2+) and (Ru(NH3)6)(3+) with (RuCl(NH3)5)(2+) as main product;;

DOI:10.1021/ja01063a008

Reference yield:

pentaammine(histidine)ruthenium(II) (81845-34-3) + hydrogen cation → pentaammine ruthenium(III) chloride (21560-19-0) + aquapentaammineruthenium(II)(2+) (21393-88-4) + trans-tetraammineaquo(2-histidinium)ruthenium(II) (81802-53-1)

Guidance literature:

With H₂O; In water; soln. of Ru complex acidified; not isolated, detected by UV; Kinetics;

upstream raw materials:

pentaammine(histidine)ruthenium(II)

[Ru(NH₃)5(NHC(O)-bz-2-CN)]⁽²⁺⁾

Downstream raw materials:

pentaammine ruthenium(III) chloride

aquapentaammineruthenium(III)

cobalt(II)

{(NH₃)5Ru(benzoquinone diimine)Ru(NH₃)5}⁽⁵⁺⁾

Refernces

• 1、 Tweedle,Taube. "Reactivity of imidazoliumruthenium ammine complexes: Nitrogen- to carbon-bound rearrangement, trans labilization, and redox behavior". . p. 3361 - 3371. Retrieved 2008/10/08.