(S)-methyl 2-methylcarbonyloxypropanoate

Base Information

Chemical Name:(S)-methyl 2-methylcarbonyloxypropanoate
CAS No.:14031-88-0
Molecular Formula:C6H10O4
Molecular Weight:146.143
Hs Code.:
DSSTox Substance ID:DTXSID70453327
Nikkaji Number:J1.153.871A
Wikidata:Q82274448
Mol file:14031-88-0.mol

Synonyms:Methyl (S)-2-acetoxypropanoate;14031-88-0;(S)-methyl 2-methylcarbonyloxypropanoate;methyl (2S)-2-acetyloxypropanoate;Propanoic acid, 2-(acetyloxy)-, methyl ester, (2S)-;SCHEMBL5864497;DTXSID70453327;QTFFGYLLUHQSAS-BYPYZUCNSA-N;methyl (2S)-2-(acetyloxy)propanoate;(S)-2-Acetoxypropanoic acid methyl ester;BS-49011;CS-0161605;E75617

Suppliers and Price of (S)-methyl 2-methylcarbonyloxypropanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (S)-methyl 2-methylcarbonyloxypropanoate

Chemical Property:

XLogP3:0.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:146.05790880
Heavy Atom Count:10
Complexity:141

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C(=O)OC)OC(=O)C
Isomeric SMILES:C[C@@H](C(=O)OC)OC(=O)C

Technology Process of (S)-methyl 2-methylcarbonyloxypropanoate

There total 11 articles about (S)-methyl 2-methylcarbonyloxypropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 17094-21-2
2-methyl-acetoacetic acid methyl ester

: 14031-88-0
(S)-O-Acetyllactic acid Methyl Ester

Guidance literature:: With phenylacetone monooxygenase from Thermobifida fusca; glucose-6-phosphate dehydrogenase; glucose-6-phosphate; NADPH; In dimethyl sulfoxide; at 30 ℃; for 24h; pH=9; optical yield given as %ee; enantioselective reaction; aq. buffer; Enzymatic reaction;
DOI:10.1002/anie.201103348

Reference yield:

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 85828-09-7
(-)-α-(2-Furyl)ethyl acetate

: 14031-88-0
(S)-O-Acetyllactic acid Methyl Ester

Guidance literature:: With sodium periodate; ruthenium tetroxide; Yield given. Multistep reaction; 1.) CCl₄, MeCN, H₂O, 44 h, room temp., 2.) ether;
DOI:10.1021/jo00162a009

Reference yield:

: 686-46-4
methyl 2-acetoxyacrylate

: 14031-88-0
(S)-O-Acetyllactic acid Methyl Ester

: 60426-97-3
(R)-O-Acetyllactic acid Methyl Ester

Guidance literature:: With rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate; diphosphines type FERRIPHOS ligand; hydrogen; In acetone; for 12h; under 750.06 Torr; Yield given; Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;
DOI:10.1016/S0957-4166(99)00182-2