Stannane, (2-bromophenyl)trimethyl-

Base Information

Chemical Name:Stannane, (2-bromophenyl)trimethyl-
CAS No.:14076-21-2
Molecular Formula:C9H13BrSn
Molecular Weight:319.816
Hs Code.:

Synonyms:

Suppliers and Price of Stannane, (2-bromophenyl)trimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Stannane, (2-bromophenyl)trimethyl-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Stannane, (2-bromophenyl)trimethyl-

There total 2 articles about Stannane, (2-bromophenyl)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 14275-62-8
1,2-bis(trimethylstannyl)benzene

: 14076-21-2
1-bromo-2-(trimethylstannyl)benzene

Guidance literature:: With bromine; In methanol; diethyl ether; at -75°C;;
DOI:10.1021/ja00980a037

Reference yield: 38.0%

: 1066-45-1
trimethyltin(IV)chloride

: 583-53-9
2,3-dibromobenzene

: 14076-21-2
1-bromo-2-(trimethylstannyl)benzene

Guidance literature:: With Mg; NH₄Cl; 1,2-dibromoethane; In diethyl ether; using high-vac. techniques; mixt. of C6H4(Br)2, C2H4Br2, Et2O added to sublimed Mg covered with Et2O in 2 h at 0°C; stirred for 1.5 h at 0°C; Me3SnCl in Et2O added over 1 h; stirred for 20 h at room temp.; satd. NH4Cl added; org. fraction sepd.; aq. fraction extd. (Et2O); extracts combined; washed (H2O); dried (MgSO4); filtered; evapd. to dryness; residual oil purified by high-vac. distn.; collected at 49°C at 0.08 mbar; as oil; elem. anal.;
DOI:10.1021/om011083a

Reference yield: 77.0%

: 14076-21-2
1-bromo-2-(trimethylstannyl)benzene

: 1529-47-1
chlorotrimethylgermane

: 436850-38-3
1-trimethylgermyl-2-(trimethylstannyl)benzene

: 14275-62-8
1,2-bis(trimethylstannyl)benzene

: 31608-65-8
1,2-bis(trimethylgermyl)benzene

Guidance literature:: With Mg; NH₄Cl; 1,2-dibromoethane; In tetrahydrofuran; using high-vac. techniques; mixt. of C6H4(Br)(SnMe3), C2H4Br2 added to sublimed Mg covered with THF; stirred for 1.5 h at room temp.; mixt. hydrolyzed; quenched with Me3GeCl; satd. NH4Cl added; org. fraction sepd.; aq. fraction extd. (Et2O); extracts combined; washed (H2O); dried (MgSO4); filtered; evapd. to dryness; monitored by NMR; elem. anal.;
DOI:10.1021/om011083a