Bis[2,4,6-tri(propan-2-yl)phenyl]germane

Base Information

Chemical Name:Bis[2,4,6-tri(propan-2-yl)phenyl]germane
CAS No.:141376-82-1
Molecular Formula:C30H48Ge
Molecular Weight:481.301
Hs Code.:
DSSTox Substance ID:DTXSID10770247
Mol file:141376-82-1.mol

Synonyms:Bis[2,4,6-tri(propan-2-yl)phenyl]germane;141376-82-1;DTXSID10770247;bis(2,4,6-triisopropylphenyl)-lambda2-germane

Suppliers and Price of Bis[2,4,6-tri(propan-2-yl)phenyl]germane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of Bis[2,4,6-tri(propan-2-yl)phenyl]germane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:8
Exact Mass:480.2811292
Heavy Atom Count:31
Complexity:435

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)C1=CC(=C(C(=C1)C(C)C)[Ge]C2=C(C=C(C=C2C(C)C)C(C)C)C(C)C)C(C)C

Technology Process of Bis[2,4,6-tri(propan-2-yl)phenyl]germane

There total 2 articles about Bis[2,4,6-tri(propan-2-yl)phenyl]germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

: 141376-88-7
(chlorodimesitylsilyl)bis(2,4,6-triisopropylphenyl)germane

: 141396-47-6
(dimesitylsilyl)bis(2,4,6-triisopropylphenyl)germane

: 141376-82-1
bis(2,4,6-triisopropylphenyl)germane

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; pentane; addn. of t-BuLi in pentane to a soln. of the silylgermane in anhyd. THF at -23°C under dry Ar, warming to 20°C, stirring (5.5 h) yielding a red-brown soln., addn. of methanol, immediate color change to pale yellow; aq. workup, chromy.; elem. anal.;
DOI:10.1021/om00042a035

Reference yield:

: 16853-85-3
lithium aluminium tetrahydride

: 21524-34-5
2,4,6-triisopropyl-1-bromobenzene

: 10038-98-9
germaniumtetrachloride

: 141376-82-1
bis(2,4,6-triisopropylphenyl)germane

Guidance literature:: 2,4,6-triisopropyl-1-bromobenzene; With magnesium; In tetrahydrofuran; at 20 ℃; for 3h; Reflux; Inert atmosphere;

germaniumtetrachloride; In benzene; at 80 ℃; for 17h; Inert atmosphere;

lithium aluminium tetrahydride; In tetrahydrofuran; at 0 ℃; for 4h; Reflux; Inert atmosphere;
DOI:10.1021/acs.organomet.7b00470

Reference yield: 70.0%

: 141376-82-1
bis(2,4,6-triisopropylphenyl)germane

: 5599-27-9
dichloro(dimesityl)silane

: 141376-88-7
(chlorodimesitylsilyl)bis(2,4,6-triisopropylphenyl)germane

Guidance literature:: With hydrogenchloride; tert.-butyl lithium; In tetrahydrofuran; addn. of t-BuLi in pentanes to a soln. of the diarylgermane in THF at -23°C under dry Ar, stirring (1 h), dropwise addn. of the yellow soln. to Mes2SiCl2 in THF at -23°C, warming to room temp., stirring (overnight), addn. of 3 M HCl; extg. (Et2O), drying the org. layer (over MgSO4), filtration, removing solvent, chromy.; elem. anal.;
DOI:10.1021/om00042a035