[1,1-Bis(phenylsulfanyl)butyl](tributyl)stannane

Base Information

Chemical Name:[1,1-Bis(phenylsulfanyl)butyl](tributyl)stannane
CAS No.:142073-41-4
Molecular Formula:C₂₈H₄₄S₂Sn
Molecular Weight:563.499
Hs Code.:
DSSTox Substance ID:DTXSID70569699
Wikidata:Q82456901

Synonyms:142073-41-4;[1,1-Bis(phenylsulfanyl)butyl](tributyl)stannane;DTXSID70569699

Suppliers and Price of [1,1-Bis(phenylsulfanyl)butyl](tributyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [1,1-Bis(phenylsulfanyl)butyl](tributyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:16
Exact Mass:564.190646
Heavy Atom Count:31
Complexity:399

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C(CCC)(SC1=CC=CC=C1)SC2=CC=CC=C2

Technology Process of [1,1-Bis(phenylsulfanyl)butyl](tributyl)stannane

There total 1 articles about [1,1-Bis(phenylsulfanyl)butyl](tributyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 55110-80-0
Li⁽¹⁺⁾*CH₃CH₂CH₂C(SC₆H₅)2^(1-) = Li(CH₃CH₂CH₂C(SC₆H₅)2)

: 1461-22-9
tributyltin chloride

: 142073-41-4
CH₃CH₂CH₂C(SC₆H₅)2(Sn(C₄H₉)3)

Guidance literature:: In tetrahydrofuran; -40°C; 1 h;
DOI:10.1246/cl.1992.819

Reference yield: 94.0%

: 142073-41-4
CH₃CH₂CH₂C(SC₆H₅)2(Sn(C₄H₉)3)

: 6651-36-1
1-(Trimethylsilyloxy)cyclohexene

: 7646-78-8
tin(IV) chloride

: CH₃CH₂CH₂C(SC₆H₅)(Sn(C₄H₉)3)(C₆H₉O)

Guidance literature:: In dichloromethane; to a CH2Cl2 solution of the α-tributylstannylthioacetal and the silyl-compound was added SnCl4 in CH2Cl2 at -78°C; stirring for 5 h; addition of water; extraction with CH2Cl2; dried (Na2SO4); condensed under reduced pressure; residue was purified by silica-gel chromatography (hexane:AcOEt = 98:2); IR, NMR;
DOI:10.1246/cl.1992.819

Reference yield: 76.0%

: 13735-81-4
1-styrenyloxytrimethylsilane

: 142073-41-4
CH₃CH₂CH₂C(SC₆H₅)2(Sn(C₄H₉)3)

: 7646-78-8
tin(IV) chloride

: 142073-48-1
CH₃CH₂CH₂C(SC₆H₅)(Sn(C₄H₉)3)(CH₂C(O)C₆H₅)

Guidance literature:: In dichloromethane; to a CH2Cl2 solution of the α-tributylstannylthioacetal and the silyl-compound was added SnCl4 in CH2Cl2 at -78°C; stirring for 5 h; addition of water; extraction with CH2Cl2; dried (Na2SO4); condensed under reduced pressure; residue was purified by silica-gel chromatography (hexane:AcOEt = 98:2); IR, NMR;
DOI:10.1246/cl.1992.819