Einecs 215-689-5

Base Information

• Chemical Name: Einecs 215-689-5
• CAS No.: 7646-78-8
• Molecular Formula: Cl4Sn
• Molecular Weight: 260.522
• Hs Code.: 2827.39
• European Community (EC) Number: 215-689-5
• UNII: 67H76LFL3V
• Nikkaji Number: J3.743E
• Mol file: 7646-78-8.mol

Synonyms:1344-13-4;EINECS 215-689-5;STANNIC CHLORIDE [MI];STANNIC CHLORIDE [HSDB];BP-20399;T2053;Tin(IV) Chloride (ca. 1.0mol/L in Dichloromethane)

Chemical Property of Einecs 215-689-5

Chemical Property:

• Appearance/Colour: Clear to slightly yellow fuming liquid
• Vapor Pressure: 10 mm Hg ( 10 °C)
• Melting Point: -33 °C(lit.)
• Refractive Index: 1.512
• Boiling Point: 114.1 °C at 760 mmHg
• Flash Point: 34°F
• PSA: 0.00000
• Density: 2.226
• LogP: 2.37720
• Storage Temp.: Store at RT.
• Sensitive.: Air Sensitive
• Solubility.: Miscible with alcohol, benzene, toluene, chloroform, acetone, ca
• Water Solubility.: reacts
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 261.774663
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Tin(IV) chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,T,F
• Hazard Codes: C,T,F,N
• Statements: 34-52/53-40-23/24/25-11-67-37-65-50/53
• Safety Statements: 26-45-61-7/8-36/37-24/25-23-36/37/39-16-62

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[Sn+4]
• Uses: Tin(IV) chloride is a mordant for dying fabrics; a stabilizer for perfume in soap; used in weighting silk; in ceramic coatings; in manufacturing blue print papers; and to produce fuchsin. Also, tin(IV) chloride is used in preparing many organotin compounds. Tin(IV) chloride is a precursor to prepare organotin compounds such as tetralkyltin and dialkyldichlorotin(IV), which find applications as catalysts and polymer stabilizers. As a Lewis acid catalyst, it is used in Fridel-Crafts reactions for alkylation and cyclization. It is involved in the selective nitration of aromatic compounds in the presence of fuming nitric acid. Furthermore, it is used to prepare tin(IV) oxide coating by sol-gel process. Electroconductive and electroluminescent coatings, mordant in dyeing textiles, perfume stabilization, manufacture of fuchsin, color lakes, ceramic coatings, bleaching agent for sugar, stabilizer for certain resins, manufacture of blueprint and other sensitized papers, other tin salts, bacteria and fungi control in soaps
• Description: Tin (IV) chloride appears as white crystals with a strong pungent chlorine odour. On heating, tin (IV) chloride decomposition emits acrid fumes. At room temperature, it is colourless and releases fumes on contact with air, giving a stinging odour. Stannic chloride was used as a chemical weapon during World War I. It is also used in the glass container industry for making an external coating that toughens the glass. Stannic chloride is used in chemical reactions with fuming (90%) nitric acid for the selective nitration of activated aromatic rings in the presence of unactivated ones. Tin (IV) chloride reacts violently with water or moist air to produce corrosive hydrogen chloride. Tin (IV) chloride reacts with turpentine, alcohols, and amines, causing fire and explosion hazard. It attacks many metals, some forms of plastic, rubber, and coatings.
• Physical properties: Colorless fuming liquid; corrosive; density 2.234 g/mL; freezes at -33°C; boils at 114.15°C; critical temperature 318.75°C; critical pressure 37.98 atm; critical volume 351 cm3/mol; soluble in cold water, evolving heat; decomposed by hot water; soluble in alcohol, benzene, toluene, chloroform, acetone and kerosene The pentahydrate is a yellowish-white crystalline solid or small, fused lumps; faint odor of HCl; density 2.04 g/cm3; decmposes at 56°C; very soluble in water; soluble in ethanol.

Technology Process of Einecs 215-689-5

There total 267 articles about Einecs 215-689-5 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

ethyl nitrate (625-58-1) + tin(ll) chloride → hydroxylamine hydrochloride (5470-11-1) + ammonia (7664-41-7) + tin(IV) chloride (7646-78-8)

Guidance literature:

With hydrogenchloride; In hydrogenchloride; byproducts: C2H5OH, H2O; in concd. HCl soln.; evapn. of the alcohol,diluting with water,pptg. of the Sn with H2S,evapn. and crystn. from alcohol;

Reference yield: 84.1%

tetrachloromethane (56-23-5) + tetraphenyltin(IV) (595-90-4) + dibenzoyl peroxide (94-36-0) → hexachloroethane (67-72-1) + tin(IV) chloride (7646-78-8) + chlorobenzene (108-90-7) + benzene-1,2-dicarboxylic acid (88-99-3,73607-73-5) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

50h boiling;

Reference yield:

indium(III) oxide + chlorine (7782-50-5) + tin(IV) oxide → In2Cl6 (27693-84-1,21563-01-9) + indium(III) chloride (10025-82-8) + tin(IV) chloride (7646-78-8)

Guidance literature:

In neat (no solvent); byproducts: O2; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2 flow 100 ml/min); chem. anal.; Kinetics;

upstream raw materials:

ethyl chlorosulfate

iodine

ethanol

tetraphenyltin(IV)

Downstream raw materials:

1,2,3,4-tetra-O-acetyl-6-O-p-tolylsulfonyl-α-D-glucopyranose

3-acetyl-2-ethylbenzofuran

2-chloro-1-acetoxyethane

4-Chlorobutyl acetate

Refernces

• 1、 Mamedova,Ragimov,Sadykhov,Aliev. "Preparation and physicochemical study of nickel(II) thiostannate in the NiCl2-SnS2-H2O system". . p. 160 - 162. Retrieved 2012.
• 2、 Janiak, Tadeusz,Blazejowski, Jerzy. "". . p. 137 - 154. Retrieved 1990.
• 3、 Hubbard, R. A.,Luder, W. F.. "". . p. 1327 - 1329. Retrieved 1951.
• 4、 Hoenig, Alfred. "". . p. 441 - 457. Retrieved 1915.
• 5、 FONSTAD CG,LINZ A,REDIKER RH. "VAPOR PHASE GROWTH OF STANNIC OXIDE SINGLE CRYSTALS". . p. 1269 - 1271. Retrieved 1969.
• 6、 Shinohara, Nobuyoshi,Mori, Katsuhiko,Inoue, Makoto. "AQUEOUS CHEMISTRY OF TIN(III). A FLASH PHOTOLYSIS STUDY". . p. 661 - 664. Retrieved 1986.
• 7、 Dunstan, Pedro Oliver. "Thermochemistry of adducts of tin(IV) chloride with heterocyclic bases". . p. 1 - 7. Retrieved 2003.
• 8、 Lo Fiego, Marcos J.,Badajoz, Mercedes A.,Domini, Claudia,Chopa, Alicia B.,Lockhart, María T.. "Indium-mediated regioselective synthesis of ketones from arylstannanes under solvent-free ultrasound irradiation". . p. 826 - 832. Retrieved 2013/03/14.