1,2-Cyclohexanediol, 4-ethenyl-

Base Information

• Chemical Name: 1,2-Cyclohexanediol, 4-ethenyl-
• CAS No.: 31646-64-7
• Molecular Formula: C8H14 O2
• Molecular Weight: 142.198
• European Community (EC) Number: 630-922-4
• DSSTox Substance ID: DTXSID50953613
• Nikkaji Number: J634.169A
• Mol file: 31646-64-7.mol

Synonyms:4-ethenylcyclohexane-1,2-diol;1,2-Cyclohexanediol, 4-ethenyl-;31646-64-7;4-Ethenyl-1,2-cyclohexanediol;4-vinylcyclohexane-1,2-diol;SCHEMBL2712241;DTXSID50953613;1,2-dihydroxy-4-vinylcyclohexane;BSJHRRSHDADBTA-UHFFFAOYSA-N

Chemical Property of 1,2-Cyclohexanediol, 4-ethenyl-

Chemical Property:

• Vapor Pressure: 0.0333mmHg at 25°C
• Boiling Point: 214.8°Cat760mmHg
• Flash Point: 94.2°C
• PSA: 40.46000
• Density: 1.172g/cm³
• LogP: 0.69430
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 142.099379685
• Heavy Atom Count: 10
• Complexity: 122

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC1CCC(C(C1)O)O

Technology Process of 1,2-Cyclohexanediol, 4-ethenyl-

There total 10 articles about 1,2-Cyclohexanediol, 4-ethenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

4-ethenylcyclohexene (100-40-3) → 1,2-Epoxy-4-vinylcyclohexane (106-86-5) + 3,4-dihydroxy-1-vinylcyclohexane (31646-64-7)

Guidance literature:

With dihydrogen peroxide; magnesium sulfate; methyltrioxorhenium(VII); In tert-butyl alcohol; at 15 ℃; for 2h;

Reference yield: 5.0%

1,2-Epoxy-4-vinylcyclohexane (106-86-5) → 3,4-dihydroxy-1-vinylcyclohexane (31646-64-7) + 4-azido-3-hydroxy-1-vinylcyclohexane (83185-49-3) + 3-azido-4-hydroxy-1-vinylcyclohexane (83185-50-6)

Guidance literature:

With sodium azide; In water; at 100 ℃; for 5h;

Reference yield:

4-ethenylcyclohexene (100-40-3) → 1,2-Epoxy-4-vinylcyclohexane (106-86-5) + 7,8-Epoxy-1-Cyclohexene (5116-65-4) + 3,4-dihydroxy-1-vinylcyclohexane (31646-64-7)

Guidance literature:

With [π-C5H5N(+)(CH2)15CH3]3(PMo12O40)(3-); dihydrogen peroxide; magnesium sulfate; In chloroform; at 60 ℃; for 24h; Yield given. Yields of byproduct given;

upstream raw materials:

1,2-Epoxy-4-vinylcyclohexane

4-ethenylcyclohexene

acetic acid

C₉H₁₄O₃

Downstream raw materials:

4-Ethylphenol

4-ethylcyclohexanone

4-ethylcatechol

4-(2-sulfoethyl)cyclohexane-1,2-diol sodium salt