2,3-Anthracenedicarboxylic Anhydride

Base Information

• Chemical Name: 2,3-Anthracenedicarboxylic Anhydride
• CAS No.: 6812-14-2
• Molecular Formula: C16H8 O3
• Molecular Weight: 248.238
• Hs Code.: 29189900
• European Community (EC) Number: 677-090-9
• DSSTox Substance ID: DTXSID10455128
• Mol file: 6812-14-2.mol

Synonyms:6812-14-2;Anthra[2,3-c]furan-1,3-dione;2,3-Anthracenedicarboxylic Anhydride;naphtho[2,3-f][2]benzofuran-1,3-dione;2,3-AnthracenedicarboxylicAnhydride;SCHEMBL769280;DTXSID10455128;2,3anthracenedicarboxylic anhydride;MFCD00438292;AKOS015840849;BS-44020;CS-0313924;T71216

Chemical Property of 2,3-Anthracenedicarboxylic Anhydride

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 497.482°C at 760 mmHg
• Flash Point: 256.486°C
• PSA: 43.37000
• Density: 1.453g/cm³
• LogP: 3.30360
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 248.047344113
• Heavy Atom Count: 19
• Complexity: 378

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,3-Anthracenedicarboxylic Anhydride >93.0%(GC) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C=C3C=C4C(=CC3=CC2=C1)C(=O)OC4=O

Technology Process of 2,3-Anthracenedicarboxylic Anhydride

There total 1 articles about 2,3-Anthracenedicarboxylic Anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

(+/-)-9,10-ethanoanthracene-2,3,trans-11,12-tetracarboxylic acid → 2,3-anthracenedicarboxylic acid anhydride (6812-14-2) + (2E)-but-2-enedioic acid (110-17-8,26099-09-2)

Guidance literature:

In diphenylether; Heating;

DOI:10.1016/S0040-4039(00)77055-9

Reference yield: 97.0%

2,3-anthracenedicarboxylic acid anhydride (6812-14-2) + (1R,2R)-2-aminocyclohexanol (931-15-7,931-16-8,6850-38-0,6982-39-4,33092-82-9,38898-70-3,74111-21-0,108267-20-5) → (1'R,2'R)-trans-2'-(2,3-anthracenedicarboximido)cyclohexanol (244755-79-1)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; toluene; at 140 ℃; for 16h; Dean-Stark;

DOI:10.1039/c5ob00780a

Reference yield: 93.7%

2,3-anthracenedicarboxylic acid anhydride (6812-14-2) + trans-2-aminocyclohexanol hydrochloride (5456-63-3) → trans-2-(2,3-anthracenedicarboximido)cyclohexanol

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; toluene; for 10h; Heating;

DOI:10.1271/bbb.63.1209

Downstream raw materials:

2-Benzoyl-anthracen-carbonsaeure-3

(1'R,2'R)-trans-2'-(2,3-anthracenedicarboximido)cyclohexanol

(1'S,2'S)-trans-2'-(2,3-anthracenedicarboximido)cyclohexanol

3-benzoyl-9,10-dioxo-9,10-dihydro-anthracene-2-carboxylic acid

Refernces