Phenol, 3-[[3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-2-methoxy-5-(phenyl methoxy)phenyl]methyl]-4-[(2-methoxyethoxy)methoxy]-, benzoate

Base Information

Chemical Name:Phenol, 3-[[3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-2-methoxy-5-(phenyl methoxy)phenyl]methyl]-4-[(2-methoxyethoxy)methoxy]-, benzoate
CAS No.:147067-75-2
Molecular Formula:C49H52O8Si
Molecular Weight:797.033
Hs Code.:
Mol file:147067-75-2.mol

Phenol,
3-[[3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-2-methoxy-5-(phenyl
methoxy)phenyl]methyl]-4-[(2-methoxyethoxy)methoxy]-, benzoate

Synonyms:

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Chemical Property of Phenol, 3-[[3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-2-methoxy-5-(phenyl methoxy)phenyl]methyl]-4-[(2-methoxyethoxy)methoxy]-, benzoate

Chemical Property:

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Technology Process of Phenol, 3-[[3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-2-methoxy-5-(phenyl methoxy)phenyl]methyl]-4-[(2-methoxyethoxy)methoxy]-, benzoate

There total 13 articles about Phenol, 3-[[3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-2-methoxy-5-(phenyl methoxy)phenyl]methyl]-4-[(2-methoxyethoxy)methoxy]-, benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 147067-74-1
Benzoic acid 3-bromomethyl-4-(2-methoxy-ethoxymethoxy)-phenyl ester

: 147067-71-8
(5-Benzyloxy-3-bromo-2-methoxy-benzyloxy)-tert-butyl-diphenyl-silane

: 1,2-bis(5-(benzoyloxy)-2-[(2-methoxyethoxy)methoxy]phenyl)ethane

: 147067-75-2
Benzoic acid 3-[5-benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-2-methoxy-benzyl]-4-(2-methoxy-ethoxymethoxy)-phenyl ester

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; ethylene dibromide; zinc; In tetrahydrofuran; 1.) -5 deg C, 4.75 h, 2.) 60 deg C, 17 h;
DOI:10.1021/jo970596h

Reference yield:

: 1194-98-5
2,5-Dihydroxybenzaldehyde

: 147067-75-2
Benzoic acid 3-[5-benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-2-methoxy-benzyl]-4-(2-methoxy-ethoxymethoxy)-phenyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 92 percent / Et₃N, DMAP / CH₂Cl₂ / 5 h

2: NaH, DMPU / tetrahydrofuran / -10 deg C, 45 min, -10 deg C to rt, 4 h

3: 84 percent / NaBH₄ / tetrahydrofuran; bis-(2-methoxy-ethyl) ether / 0.33 h / -78 - -45 °C

4: 89 percent / Ph₃P, NBS / tetrahydrofuran / 0.25 h / 5 °C

5: 87 percent / 1.) Zn, 1,2-dibromoethane, 2.) (Ph₃P)4Pd / tetrahydrofuran / 1.) -5 deg C, 4.75 h, 2.) 60 deg C, 17 h

With dmap; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; sodium tetrahydroborate; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydride; ethylene dibromide; triethylamine; triphenylphosphine; zinc; In tetrahydrofuran; dichloromethane; diethylene glycol dimethyl ether;
DOI:10.1021/jo970596h

Reference yield:

: 147067-92-3
2-hydroxy-5-benzoyloxybenzaldehyde

: 147067-75-2
Benzoic acid 3-[5-benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-2-methoxy-benzyl]-4-(2-methoxy-ethoxymethoxy)-phenyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: NaH, DMPU / tetrahydrofuran / -10 deg C, 45 min, -10 deg C to rt, 4 h

2: 84 percent / NaBH₄ / tetrahydrofuran; bis-(2-methoxy-ethyl) ether / 0.33 h / -78 - -45 °C

3: 89 percent / Ph₃P, NBS / tetrahydrofuran / 0.25 h / 5 °C

4: 87 percent / 1.) Zn, 1,2-dibromoethane, 2.) (Ph₃P)4Pd / tetrahydrofuran / 1.) -5 deg C, 4.75 h, 2.) 60 deg C, 17 h

With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; sodium tetrahydroborate; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydride; ethylene dibromide; triphenylphosphine; zinc; In tetrahydrofuran; diethylene glycol dimethyl ether;
DOI:10.1021/jo970596h