2-Cyclohexen-1-one, 3-(methoxymethoxy)-6-methyl-

Base Information

Chemical Name:2-Cyclohexen-1-one, 3-(methoxymethoxy)-6-methyl-
CAS No.:147728-67-4
Molecular Formula:C9H14O3
Molecular Weight:170.208
Hs Code.:
DSSTox Substance ID:DTXSID20452502
Nikkaji Number:J866.907D
Mol file:147728-67-4.mol

Synonyms:147728-67-4;2-Cyclohexen-1-one, 3-(methoxymethoxy)-6-methyl-;DTXSID20452502;3-(Methoxymethoxy)-6-methyl-2-cyclohexen-1-one

Suppliers and Price of 2-Cyclohexen-1-one, 3-(methoxymethoxy)-6-methyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2-Cyclohexen-1-one, 3-(methoxymethoxy)-6-methyl-

Chemical Property:

XLogP3:1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:170.094294304
Heavy Atom Count:12
Complexity:196

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1CCC(=CC1=O)OCOC

Technology Process of 2-Cyclohexen-1-one, 3-(methoxymethoxy)-6-methyl-

There total 1 articles about 2-Cyclohexen-1-one, 3-(methoxymethoxy)-6-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 111596-58-8
3-(methoxymethoxy)-2-cyclohexenone

: 74-88-4
methyl iodide

: 147728-67-4
6-methyl-3-methoxymethyloxy-2-cyclohexenone

Guidance literature:: 3-(methoxymethoxy)-2-cyclohexenone; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.5h;

methyl iodide; In tetrahydrofuran; at -78 - 20 ℃; for 1h;
DOI:10.1016/S0957-4166(99)00304-3

Reference yield: 60.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 147728-67-4
6-methyl-3-methoxymethyloxy-2-cyclohexenone

: 252979-14-9
(+/-)-6-hydroxymethyl-3-(methoxymethoxy)-6-methyl-2-cyclohexenone

Guidance literature:: 6-methyl-3-methoxymethyloxy-2-cyclohexenone; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.5h;

formaldehyd; In tetrahydrofuran; at -78 ℃; for 0.5h;
DOI:10.1016/S0957-4166(99)00304-3

Reference yield:

: 147728-67-4
6-methyl-3-methoxymethyloxy-2-cyclohexenone

: 123522-80-5
(R)-2-(tert-butyldiphenylsiloxymethyl)-2-methylcyclohexanone

Guidance literature:: Multi-step reaction with 4 steps

1.1: lithium diisopropylamide / tetrahydrofuran / 0.5 h / -78 °C

1.2: 60 percent / tetrahydrofuran / 0.5 h / -78 °C

2.1: 46 percent / lipase AK / benzene / 24 h / 20 °C

3.1: 76 percent / H₂; K₂CO₃ / 10 percent Pd/C / methanol / 1 h / 20 °C

4.1: 66 percent / imidazole / dimethylformamide / 1 h / 20 °C

With 1H-imidazole; lipase AK; hydrogen; potassium carbonate; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; methanol; N,N-dimethyl-formamide; benzene; 1.1: Metallation / 1.2: Formylation / 2.1: Acetylation / 3.1: Hydrogenation / 4.1: Condensation;
DOI:10.1016/S0957-4166(99)00304-3