Rhodium, carbonylchlorobis(ethyldiphenylphosphine)-

Base Information

Chemical Name:Rhodium, carbonylchlorobis(ethyldiphenylphosphine)-
CAS No.:14875-00-4
Molecular Formula:C₂₉H₃₀ClOP₂Rh
Molecular Weight:594.863
Hs Code.:
Mol file:14875-00-4.mol

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Rhodium, carbonylchlorobis(ethyldiphenylphosphine)-

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Technology Process of Rhodium, carbonylchlorobis(ethyldiphenylphosphine)-

There total 6 articles about Rhodium, carbonylchlorobis(ethyldiphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 607-01-2
ethyl-diphenyl-phosphane

: 14875-00-4,15663-57-7
trans-[Rh(CO)Cl(ethyldiphenylphosphine)2]

Guidance literature:: With carbon monoxide; In benzene; byproducts: COD; absence of air; dropwise addn. of slight excess of phosphine to Rh-complex (in CO-atmosphere), stirring for 40 min; crystn. on addn. of light petroleum;
DOI:10.1039/DT9770000120

Reference yield: 85.0%

: di-μ-chloro-bis[bis(cyclo-octene)rhodium]

: 607-01-2
ethyl-diphenyl-phosphane

: 14875-00-4,15663-57-7
trans-[Rh(CO)Cl(ethyldiphenylphosphine)2]

Guidance literature:: With CO; In light petroleum; stirring Rh-complex with organic compound in light petroleum under argon for 20 h, removing solvent in vac., dissolving product in Et2O, bubbling CO through the soln. for 5 min; concg., holding at -30°C for 18 h, filtn., washing (cold Et2O) at -50°C, drying in vac.;
DOI:10.1039/DT9940001963

Reference yield:

: 12257-42-0
[(norbornadiene)rhodium(I)chloride]2

: 607-01-2
ethyl-diphenyl-phosphane

: 14875-00-4,15663-57-7
RhCl(CO)(PEtPh₂)2

Guidance literature:: With hydrogen; In methanol; complex and ligand in soln. stirred under H2 for 30 min at 30-50°C, olefin added; evapd. (vac.), not isolated, detected by IR;
DOI:10.1016/S0022-328X(00)94429-2