nickel(2+) thiocyanate triphenylphosphane (1:2:2)

Base Information

• Chemical Name: nickel(2+) thiocyanate triphenylphosphane (1:2:2)
• CAS No.: 15709-62-3
• Molecular Formula: C₃₈H₃₀N₂NiP₂S₂
• Molecular Weight: 699.439
• Mol file: 15709-62-3.mol

Synonyms:Nickel,bis(isothiocyanato)bis(triphenylphosphine)- (8CI); Nickel,bis(thiocyanato-N)bis(triphenylphosphine)-; Nickel,diisothiocyanatobis(triphenylphosphine)- (7CI);Bis(isothiocyanato)bis(triphenylphosphine)nickel;Diisothiocyanatobis(triphenylphosphine)nickel

Chemical Property of nickel(2+) thiocyanate triphenylphosphane (1:2:2)

Chemical Property:

• Vapor Pressure: 4.74E-05mmHg at 25°C
• Boiling Point: 360°Cat760mmHg
• Flash Point: 181.7°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of nickel(2+) thiocyanate triphenylphosphane (1:2:2)

There total 8 articles about nickel(2+) thiocyanate triphenylphosphane (1:2:2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

nickel(II) thiocyanate (13689-92-4) + triphenylphosphine (603-35-0) → {Ni(SCN)2(Triphenylphosphin)2} (15709-62-3,65138-20-7)

Guidance literature:

In butan-1-ol; in boiling butanol;

DOI:10.1039/JR9580000719

Reference yield:

nickel(II) nitrate hexahydrate + potassium thioacyanate (333-20-0) → {Ni(SCN)2(Triphenylphosphin)2} (15709-62-3,65138-20-7)

Guidance literature:

With triphenylphosphine; In ethanol; treating mixt. of Ni(NO3)2 with KNCS in ethanol with PPh3 (excess); slow crystn.; elem. anal.;

DOI:10.1016/S0277-5387(00)83512-3

Reference yield:

{(C18H15P)sek.-C4H9}{NiBr3(Triphenylphosphin)} → {Ni(SCN)2(Triphenylphosphin)2} (15709-62-3,65138-20-7)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol

2: butan-1-ol

With methanol; In butan-1-ol;

upstream raw materials:

potassium thioacyanate

nickel(II) thiocyanate

triphenylphosphine

dibromobis(triphenylphosphine)nickel(II)

Downstream raw materials:

Ni(OP(C₆H₅)3)2(NCS)2

Refernces

• 1、 Lomjansky, Dominik,Rajnák, Cyril,Titi?, Ján,Monco?, Ján,Smolko, Luká?,Bo?a, Roman. "Impact of tetrahedral and square planar geometry of Ni(II) complexes with (pseudo)halide ligands to magnetic properties". . p. 352 - 358. Retrieved 2018/10/05.