2-Allyloxyphenylboronic acid

Base Information

Chemical Name:2-Allyloxyphenylboronic acid
CAS No.:151414-76-5
Molecular Formula:C9H11BO3
Molecular Weight:177.996
Hs Code.:2931900090
European Community (EC) Number:874-405-3
DSSTox Substance ID:DTXSID90476275
Nikkaji Number:J1.820.091K
Wikidata:Q82307353
Mol file:151414-76-5.mol

Synonyms:2-ALLYLOXYPHENYLBORONIC ACID;151414-76-5;(2-prop-2-enoxyphenyl)boronic acid;[2-(prop-2-en-1-yloxy)phenyl]boronic acid;Boronic acid, B-[2-(2-propen-1-yloxy)phenyl]-;Boronic acid, [2-(2-propenyloxy)phenyl]-;DTXSID90476275;2-ALLYLOXYPHENYLBORONICACID;BGA41476;MFCD11183169;AKOS009319631;BS-21537;CS-0178782;E84486;EN300-7116983;A935773;Z381513062

Suppliers and Price of 2-Allyloxyphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-AllyloxyphenylboronicAcid
250mg
$ 435.00

TRC
2-AllyloxyphenylboronicAcid
1g
$ 965.00

Crysdot
2-Allyloxyphenylboronicacid 95+%
1g
$ 520.00

AK Scientific
2-Allyloxyphenylboronicacid
1g
$ 517.00

Total 8 raw suppliers

Chemical Property of 2-Allyloxyphenylboronic acid

Chemical Property:

Boiling Point:351.8±44.0 °C(Predicted)
PKA:8.59±0.53(Predicted)
PSA：49.69000
Density:1.12±0.1 g/cm3(Predicted)
LogP:-0.06880
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:178.0801244
Heavy Atom Count:13
Complexity:161

Purity/Quality:

97% ^*data from raw suppliers

2-AllyloxyphenylboronicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B(C1=CC=CC=C1OCC=C)(O)O

Technology Process of 2-Allyloxyphenylboronic acid

There total 4 articles about 2-Allyloxyphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 5419-55-6
Triisopropyl borate

: 60333-75-7
O-allyl-2-bromophenol

: 151414-76-5
o-(prop-2-enyloxy)phenylboronic acid

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; BuLi in hexane is added to a soln. of ether-compd. in THF at -78°C, the mixt. is stirred for 1 h under N2, triisopropyl borate is added and the mixt. is stirred for 1,5 h, then warmed to room temp, HCl and Et2O is added; the organic layer is separated and washed with HCl and water, the solvent is evaporated, the residue is stirred with light petroleum at 0°C, the ppt. is washed with ice cold light petroleum, crystn. from CHCl3-light petroleum, elem. anal.;
DOI:10.1039/P19930001673