[1-(Hydroxymethyl)-4-methylcyclohex-3-en-1-yl]methanol

Base Information

Chemical Name:[1-(Hydroxymethyl)-4-methylcyclohex-3-en-1-yl]methanol
CAS No.:15827-42-6
Molecular Formula:C9H16O2
Molecular Weight:156.225
Hs Code.:
DSSTox Substance ID:DTXSID901286141
Nikkaji Number:J2.767.573E
Mol file:15827-42-6.mol

Synonyms:(4-methylcyclohex-3-ene-1,1-diyl)dimethanol;15827-42-6;[1-(hydroxymethyl)-4-methylcyclohex-3-en-1-yl]methanol;4-methyl-3-cyclohexene-1,1-dimethanol;4,4-Di(hydroxymethyl)-1-methyl-1-cyclohexene;SCHEMBL1073592;DTXSID901286141;BBL028923;STL371293;AKOS006241280;VS-09028;CS-0447601

Suppliers and Price of [1-(Hydroxymethyl)-4-methylcyclohex-3-en-1-yl]methanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of [1-(Hydroxymethyl)-4-methylcyclohex-3-en-1-yl]methanol

Chemical Property:

XLogP3:0.4
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:156.115029749
Heavy Atom Count:11
Complexity:157

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CCC(CC1)(CO)CO

Technology Process of [1-(Hydroxymethyl)-4-methylcyclohex-3-en-1-yl]methanol

There total 5 articles about [1-(Hydroxymethyl)-4-methylcyclohex-3-en-1-yl]methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 2698-65-9
4-methylcyclohex-3-ene-1,1-dicarboxylic acid diethyl ester

: 15827-42-6
1,1-bis(hydroxymethyl)-4-methylcyclohex-3-ene

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; for 3h; Inert atmosphere;
DOI:10.1016/j.chembiol.2019.10.009

Reference yield:

: 78-79-5,9003-31-0
isoprene

: 15827-42-6
1,1-bis(hydroxymethyl)-4-methylcyclohex-3-ene

Guidance literature:: Multi-step reaction with 2 steps

1: zinc(II) chloride / tetrahydrofuran / 24 h / 70 °C

2: lithium aluminium tetrahydride / diethyl ether / 3 h / 0 °C / Inert atmosphere

With lithium aluminium tetrahydride; zinc(II) chloride; In tetrahydrofuran; diethyl ether;
DOI:10.1016/j.chembiol.2019.10.009

Reference yield:

: 78-79-5,9003-31-0
isoprene

: 15827-42-6
1,1-bis(hydroxymethyl)-4-methylcyclohex-3-ene

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / 100 °C / Heating

2: 71 percent / LAH / tetrahydrofuran / -78 °C

With lithium aluminium tetrahydride; In tetrahydrofuran; 1: Diels-Alder cycloaddition;
DOI:10.1016/j.bmcl.2004.12.077