Benzene, 1-iodo-2-(2-methyl-2-propenyl)-

Base Information

• Chemical Name: Benzene, 1-iodo-2-(2-methyl-2-propenyl)-
• CAS No.: 162009-34-9
• Molecular Formula: C10H11I
• Molecular Weight: 258.102
• DSSTox Substance ID: DTXSID80453555
• Nikkaji Number: J730.294K
• Wikidata: Q82274718
• Mol file: 162009-34-9.mol

Synonyms:Benzene, 1-iodo-2-(2-methyl-2-propenyl)-;162009-34-9;2-methallyliodobenzene;DTXSID80453555;2-Methyl-3-(2-iodophenyl)-1-propene

Chemical Property of Benzene, 1-iodo-2-(2-methyl-2-propenyl)-

Chemical Property:

• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 257.99055
• Heavy Atom Count: 11
• Complexity: 140

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)CC1=CC=CC=C1I

Technology Process of Benzene, 1-iodo-2-(2-methyl-2-propenyl)-

There total 1 articles about Benzene, 1-iodo-2-(2-methyl-2-propenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

isopropenylmagnesium bromide (13291-18-4) + 2-(chloromethyl)iodobenzene (59473-45-9) → 2-methallyliodobenzene (162009-34-9)

Guidance literature:

2-(chloromethyl)iodobenzene; With [2,2]bipyridinyl; copper(l) iodide; In benzene; at 0 ℃;

isopropenylmagnesium bromide; In tetrahydrofuran; benzene; Heating;

DOI:10.1016/S0040-4020(00)01103-0

Reference yield: 86.0%

carbon monoxide (201230-82-2) + sodium tetraphenyl borate (143-66-8) + 2-methallyliodobenzene (162009-34-9) → 2-methyl-2-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-inden-1-one

Guidance literature:

palladium diacetate; triphenylphosphine; In various solvent(s); at 120 ℃; for 6h; under 760 Torr;

DOI:10.1016/S0040-4039(00)78369-9

Reference yield: 60.0%

diphenyl acetylene (501-65-5) + 2-methallyliodobenzene (162009-34-9) → 10a-Methyl-5-phenyl-10a,11-dihydro-10H-benzo[b]fluorene

Guidance literature:

With triphenylphosphine; palladium diacetate; In various solvent(s); at 130 ℃; for 48h;

DOI:10.1016/0040-4039(96)00556-4

upstream raw materials:

isopropenylmagnesium bromide

2-(chloromethyl)iodobenzene