CESIUM PERCHLORATE

Base Information

• Chemical Name: CESIUM PERCHLORATE
• CAS No.: 13454-84-7
• Deprecated CAS: 2102680-70-4
• Molecular Formula: ClCsO4
• Molecular Weight: 232.356
• Hs Code.: 29173995
• European Community (EC) Number: 236-643-0
• DSSTox Substance ID: DTXSID50884610
• Nikkaji Number: J43.762J
• Wikipedia: Caesium perchlorate
• Wikidata: Q3178745
• Mol file: 13454-84-7.mol

Synonyms:Cesiumperchlorate (6CI,7CI);Perchloric acid, cesium salt (8CI,9CI);Cesium perchlorate (CsClO4);

Chemical Property of CESIUM PERCHLORATE

Chemical Property:

• Appearance/Colour: White crystals or crystalline powder
• Melting Point: 250 ºC(lit.)
• PSA: 74.27000
• Density: 3.327 g/cm³
• LogP: 0.21430
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 231.8539631
• Heavy Atom Count: 6
• Complexity: 118

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cesium perchlorate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O
• Hazard Codes: O
• Statements: 8
• Safety Statements: 17

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [O-]Cl(=O)(=O)=O.[Cs+]
• Uses: (Cesium perchlorate) Investigations of ionic conductivity in orientationally disordered phases1Used for:? ;Long-duration optical transmission of information with infofuses2? ;Modifier of polymer electrolyte/luminescent conjugated polymer mixed ionic-electronic conductors3? ;Studies involving pH-dependent mass and volume changes of polypyrrole / poly(styrene sulfonate)4? ;Cationic effects in polymer light-emitting electrochemical cells5Reactant for investigating metal salt effects on morphology of silica nanomaterials prepared by polymerization on hydrogels6 Cesium perchlorate is used for long-duration optical transmission of information with infofuses. It is a modifier of polymer electrolyte/luminescent conjugated polymer mixed ionic-electronic conductors. It has been used as a reactant for investigating metal salt effects on morphology of silica nanomaterials prepared by polymerization on hydrogels. Investigations of ionic conductivity in orientationally disordered phasesUsed for:Long-duration optical transmission of information with infofusesModifier of polymer electrolyte/luminescent conjugated polymer mixed ionic-electronic conductorsStudies involving pH-dependent mass and volume changes of polypyrrole / poly(styrene sulfonate)Cationic effects in polymer light-emitting electrochemical cellsReactant for investigating metal salt effects on morphology of silica nanomaterials prepared by polymerization on hydrogels

Technology Process of CESIUM PERCHLORATE

There total 24 articles about CESIUM PERCHLORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

ammonium perchlorate (7790-98-9) + caesium methoxide (13106-69-9) → cesium perchlorate (13454-84-7)

Guidance literature:

In methanol; byproducts: NH3, CH3OH; all manipulations in Ar atm.; soln. of CsOMe in MeOH added to soln. of NH4 compd. in MeOH at -40 - -50°C; concd., filtered or pumped to dryness at 25°C;

DOI:10.1002/1521-3749(200208)628:8<1717::AID-ZAAC1717>3.0.CO;2-C

Reference yield: 76.0%

caesium dimethylthiocarbamoylcyanoximate (264619-02-5) + Ni(2+)*C9H18N4H4*2ClO4(1-)=Ni(C9H18N4H4)(ClO4)2 → cesium perchlorate (13454-84-7) + Ni(C9H18N4H4)(ONC(CN)C(S)N(CH3)2)(1+)*ClO4(1-)=[Ni(C9H18N4H4)(ONC(CN)C(S)N(CH3)2)]ClO4

Guidance literature:

In water; acetone; addn. of aq. soln. of Cs-salt to soln. of Ni-complex in aq. acetone (30%/70%) (stirring and gentle heating); filtration off of CsClO4, concn. of filtrate, crystn. on standing at constant temp.;

Reference yield:

perchloric acid (7601-90-3) + cesium cupric chloride (18437-47-3) → hydrogenchloride (7647-01-0,15364-23-5) + cesium perchlorate (13454-84-7) + copper dichloride

Guidance literature:

In perchloric acid;

upstream raw materials:

perchloric acid

cesium cupric chloride

cesium chloride

ammonium perchlorate

Downstream raw materials:

cesium chloride

nitrogen trifluoride

cesium hexafluoroantimonate

chlorine tetroxide fluoride

Refernces

• 1、 Willard, H. H.,Smith, G. F.. "". . p. 286 - 286. Retrieved 1923.
• 2、 Domasevich,Ponomareva,Skopenko,Zan,Siler. "N,N-Dimethylthioamidecyanooximato Nickel(II) Complex Containing a Saturated Tetraamine Macrocycle, [Ni[13]aneN4{ONC(CN)C(S)N(CH3)2}]CIO 4: Synthesis, Spectra, and Structure". . p. 1014 - 1018. Retrieved 2008/10/08.
• 3、 Benko, Jan,Vollarova, Ol'ga,Cernusak, Ivan,Pappova, Adriana. "Transfer Gibbs energies for ClO3-, BrO3-, IO3-, ClO4- and IO4- anions for water-methanol and water-propan-2-ol mixtures: Some quantum-chemical aspects of ionic solvation". . p. 4935 - 4941. Retrieved 2007/10/03.