9(10H)-Acridinone, 2,7-dibromo-10-methyl-

Base Information

• Chemical Name: 9(10H)-Acridinone, 2,7-dibromo-10-methyl-
• CAS No.: 17014-39-0
• Molecular Formula: C14H9Br2NO
• Molecular Weight: 367.03500
• Hs Code.: 2933990090
• DSSTox Substance ID: DTXSID90348221
• Nikkaji Number: J129.636A
• Wikidata: Q82122876
• Mol file: 17014-39-0.mol

Synonyms:17014-39-0;2,7-Dibromo-10-methylacridin-9(10H)-one;2,7-dibromo-10-methylacridin-9-one;9(10H)-Acridinone, 2,7-dibromo-10-methyl-;9-Acridanone, 2,7-dibromo-10-methyl-;2,7-Dibromo-10-methylacridone;SCHEMBL14479468;DTXSID90348221;2,7-Dibromo-10-methyl-9(10H)-acridinone #

Chemical Property of 9(10H)-Acridinone, 2,7-dibromo-10-methyl-

Chemical Property:

• Melting Point: 282-283 °C
• Boiling Point: 478.4±45.0 °C(Predicted)
• PKA: -3.85±0.20(Predicted)
• PSA: 22.00000
• Density: 1.781±0.06 g/cm3(Predicted)
• LogP: 4.21670
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 366.90304
• Heavy Atom Count: 18
• Complexity: 319

Purity/Quality:

2,7-Dibromo-10-methylacridone ≥95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN1C2=C(C=C(C=C2)Br)C(=O)C3=C1C=CC(=C3)Br
• Uses: 2,7-Dibromo-10-methylacridone is a versatile intermediate for the synthesis of acridinium-based photocatalysts.

Technology Process of 9(10H)-Acridinone, 2,7-dibromo-10-methyl-

There total 5 articles about 9(10H)-Acridinone, 2,7-dibromo-10-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

10-methyl-9, 10-dihydro-9-acridinone (719-54-0) → 2,7-dibromo-10-methylacridine-9(10H)-one (17014-39-0)

Guidance literature:

With N-Bromosuccinimide; In N,N-dimethyl-formamide; at 0 - 80 ℃;

DOI:10.1039/c0jm00275e

Reference yield:

10H-acridin-9-one (578-95-0,790240-54-9) → 2,7-dibromo-10-methylacridine-9(10H)-one (17014-39-0)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic acid; bromine

2: water; KOH-solution / anschlissenden Erhitzen auf 150grad und Behandeln des Reaktionsprodukts mit Dimethylsulfat bei 100grad

With potassium hydroxide; water; bromine; acetic acid;

DOI:10.1039/jr9530000232

Reference yield:

10-methyl-9, 10-dihydro-9-acridinone (719-54-0) + sodium acetate (127-09-3) → 2,7-dibromo-10-methylacridine-9(10H)-one (17014-39-0)

Guidance literature:

With bromine;

DOI:10.1039/jr9530000232

upstream raw materials:

10-methyl-9, 10-dihydro-9-acridinone

sodium acetate

ethanol

2,7-dibromoacridine-9(10H)-one