(3-Bromophenyl)(trimethyl)stannane

Base Information

Chemical Name:(3-Bromophenyl)(trimethyl)stannane
CAS No.:17113-76-7
Molecular Formula:C9H13BrSn
Molecular Weight:319.816
Hs Code.:
DSSTox Substance ID:DTXSID50521412
Wikidata:Q82385856
Mol file:17113-76-7.mol

Synonyms:17113-76-7;DTXSID50521412;(3-Bromophenyl)(trimethyl)stannane

Suppliers and Price of (3-Bromophenyl)(trimethyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of (3-Bromophenyl)(trimethyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:319.92227
Heavy Atom Count:11
Complexity:128

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C[Sn](C)(C)C1=CC=CC(=C1)Br

Technology Process of (3-Bromophenyl)(trimethyl)stannane

There total 4 articles about (3-Bromophenyl)(trimethyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1-(3-bromophenyl)-2-(methylsulfonyl)diazene

: 661-69-8
hexamethyldistannane

: 17113-76-7
(3-bromophenyl)trimethylstannane

Guidance literature:: In acetonitrile; at 20 ℃; Irradiation; Inert atmosphere;
DOI:10.1021/acs.orglett.9b01788

Reference yield: 37.0%

: 1066-45-1
trimethyltin(IV)chloride

: 111762-31-3
3-bromophenyl magnesium bromide

: 17113-76-7
(3-bromophenyl)trimethylstannane

Guidance literature:: In diethyl ether; refluxing for 2 h;;
DOI:10.1016/S0022-328X(00)83182-4

Reference yield: 13.0%

: 109-72-8,29786-93-4
n-butyllithium

: 17197-37-4
(3,5-dibromophenyl)trimethyltin

: (3,5-dibromophenyl)dimethylbutyltin

: 108-36-1
1,3-dibromobenzene

: 1527-99-7
n-butyltrimethyltin

: 17113-76-7
(3-bromophenyl)trimethylstannane

Guidance literature:: In diethyl ether; hexane; byproducts: C4H9Br; n-BuLi in hexane adding to an ether soln. of the stannane at -78°C, stirring for 30 min, hydrolyzing with 2 N HCl, org. layer sepg., drying over MgSO4; identified by gas chromy. and chromato-mass spectrometry;
DOI:10.1016/S0022-328X(00)99497-X