2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol

Base Information

• Chemical Name: 2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol
• CAS No.: 176776-60-6
• Molecular Formula: C20H22N2O2
• Molecular Weight: 322.4
• Mol file: 176776-60-6.mol

Synonyms:

Chemical Property of 2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

2,2'-((1E,1'E)-(trans-cyclohexane-1,2-diylbis(azanylylidene))bis(methanylylidene))diphenol 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol

There total 36 articles about 2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(±)-trans-1,2-diaminocyclohexane + salicylaldehyde (90-02-8) → (+)-N,N'-bis(salicylidene)-1,2-cyclohexanediamine (176776-60-6)

Guidance literature:

In ethanol; at 80 ℃; for 12h;

DOI:10.1016/j.apcata.2021.118477

Reference yield: 95.0%

trans cyclohexane-1,2-diamine + salicylaldehyde (90-02-8) → C20H22N2O2 (176776-60-6)

Guidance literature:

In ethanol; at 25 ℃; for 1h;

DOI:10.3390/molecules25173993

Reference yield: 92.0%

salicylaldehyde (90-02-8) + (1R,2R)-1,2-diaminocyclohexane tartrate (32044-22-7,39961-95-0) → (R,R)-N,N'-bis(salicylidene)-1,2-cyclohexanediamine (3187-83-5,41013-27-8,41013-28-9,64346-55-0,150026-23-6,133695-16-6,176776-60-6)

Guidance literature:

(1R,2R)-1,2-diaminocyclohexane tartrate; With sodium carbonate; In dichloromethane; water; for 1h;

salicylaldehyde; In dichloromethane; water; for 1h;

DOI:10.1155/2020/5414959

upstream raw materials:

(1R,2R)-1,2-diaminocyclohexane

salicylaldehyde

2-methyl-benzyl alcohol

trans-1,2-Diaminocyclohexane

Downstream raw materials:

tetramethyl (R,R)-1,2-cyclohexylenediamino-di-(R,R)-[(2-hydroxyphenyl)methylphosphonate]

tetraethyl (R,R)-1,2-cyclohexylenediamino-di-(R,R)-[(2-hydroxyphenyl)methylphosphonate]

tetraisopropyl (R,R)-1,2-cyclohexylenediamino-di-(R,R)-[(2-hydroxyphenyl)methylphosphonate]

(R,R)-1,2-cyclohexylenediamino-di-(R,R)-[(2-hydroxyphenyl)-methylphosphonic acid]