Tert-butylphenylsilane

Base Information

• Chemical Name: Tert-butylphenylsilane
• CAS No.: 17873-11-9
• Molecular Formula: C10H16Si
• Molecular Weight: 164.323
• European Community (EC) Number: 660-444-1
• Nikkaji Number: J3.155.976F
• Mol file: 17873-11-9.mol

Synonyms:tert-butylphenylsilane;AKOS024338768

Chemical Property of Tert-butylphenylsilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 164.102127045
• Heavy Atom Count: 11
• Complexity: 107

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)(C)[SiH2]C1=CC=CC=C1

Technology Process of Tert-butylphenylsilane

There total 3 articles about Tert-butylphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

phenyl-tert-butyldichlorosilane (17887-41-1) → tert-butyl(phenyl)silane (17873-11-9)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 25 ℃; for 1h; Inert atmosphere;

DOI:10.1002/anie.201207361

Reference yield: 53.0%

tert.-butyl lithium (594-19-4) + Phenyltrichlorosilane (98-13-5) → tert-butyl(phenyl)silane (17873-11-9)

Guidance literature:

tert.-butyl lithium; Phenyltrichlorosilane; In tetrahydrofuran; pentane; at 0 - 20 ℃; for 9h; Inert atmosphere;

With lithium aluminium tetrahydride; In tetrahydrofuran; pentane; at 0 - 20 ℃; for 8.5h; Inert atmosphere;

Reference yield: 16.0%

tert-butylmagnesium bromide (2259-30-5) + sodium bis(benzene-1,2-diolatophenyl)silicate (6157-41-1) → tert-butyl(phenyl)silane (17873-11-9)

Guidance literature:

In diethyl ether; at 35 ℃; for 15h;

DOI:10.1246/bcsj.61.101

upstream raw materials:

tert-butylmagnesium bromide

sodium bis(benzene-1,2-diolatophenyl)silicate

phenyl-tert-butyldichlorosilane

tert.-butyl lithium