Silane, (4-iodophenyl)trimethyl-

Base Information

• Chemical Name: Silane, (4-iodophenyl)trimethyl-
• CAS No.: 17881-56-0
• Molecular Formula: C9H13ISi
• Molecular Weight: 276.192
• DSSTox Substance ID: DTXSID60454404
• Nikkaji Number: J1.322.223A
• Wikidata: Q82275913
• Mol file: 17881-56-0.mol

Synonyms:Silane, (4-iodophenyl)trimethyl-;17881-56-0;SCHEMBL6512153;DTXSID60454404;1-Iodo-4-(trimethylsilyl)benzene

Chemical Property of Silane, (4-iodophenyl)trimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 275.98312
• Heavy Atom Count: 11
• Complexity: 120

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C1=CC=C(C=C1)I

Technology Process of Silane, (4-iodophenyl)trimethyl-

There total 5 articles about Silane, (4-iodophenyl)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

chloro-trimethyl-silane (75-77-4) + para-diiodobenzene (624-38-4,1032416-46-8) → 1-iodo-4-(trimethylsilyl)benzene (17881-56-0)

Guidance literature:

para-diiodobenzene; With n-butyllithium; In diethyl ether; hexane; at -78 - 0 ℃; for 1.5h;

chloro-trimethyl-silane; In diethyl ether; hexane; at -78 - 20 ℃; Further stages.;

DOI:10.1002/anie.200605002

Reference yield: 83.0%

1,4-bis-(trimethylsilyl)benzene (13183-70-5) → 1-iodo-4-(trimethylsilyl)benzene (17881-56-0)

Guidance literature:

With silver tetrafluoroborate; Iodine monochloride; In tetrahydrofuran; methanol; at -35 ℃; for 1h;

DOI:10.1055/s-1993-25912

Reference yield:

chloro-trimethyl-silane (75-77-4) + para-diiodobenzene (624-38-4,1032416-46-8) → 1,4-bis-(trimethylsilyl)benzene (13183-70-5) + 1-iodo-4-(trimethylsilyl)benzene (17881-56-0)

Guidance literature:

para-diiodobenzene; With [(tetrahydropyran)₄Ca(I)(CH₂SiMe₃)]; In tetrahydrofuran; at -40 ℃; for 0.166667h; Inert atmosphere; Schlenk technique;

chloro-trimethyl-silane; In tetrahydrofuran; at -40 - 20 ℃; for 0.166667h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.7b00592

upstream raw materials:

1-bromo-4-(trimethylsilyl)benzene

1,4-bis-(trimethylsilyl)benzene

chloro-trimethyl-silane

para-diiodobenzene

Downstream raw materials:

1-Chloro-2-methyl-4-(4-trimethylsilanyl-phenyl)-but-3-yn-2-ol

C₂₈H₃₀Si₂

4-iodophenyl dibromoborane

C₄₇H₆₆Si₂