Trimethyl(3-methylbut-3-en-1-yl)silane

Base Information

• Chemical Name: Trimethyl(3-methylbut-3-en-1-yl)silane
• CAS No.: 18294-00-3
• Molecular Formula: C8H18Si
• Molecular Weight: 142.316
• DSSTox Substance ID: DTXSID70498056
• Nikkaji Number: J414.355H
• Wikidata: Q63408795
• Mol file: 18294-00-3.mol

Synonyms:18294-00-3;Trimethyl(3-methylbut-3-en-1-yl)silane;2-methyl-4-trimethylsilyl butene;DTXSID70498056;3-METHYL-3-BUTENYLTRIMETHYLSILANE;Q63408795

Chemical Property of Trimethyl(3-methylbut-3-en-1-yl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 142.117777109
• Heavy Atom Count: 9
• Complexity: 97.6

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=C)CC[Si](C)(C)C

Technology Process of Trimethyl(3-methylbut-3-en-1-yl)silane

There total 3 articles about Trimethyl(3-methylbut-3-en-1-yl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2-dimethyl-3-(trimethylsilyl)propyl tosylate (226572-49-2) → 2-methyl-4-(trimethylsilyl)-2-butanol (4426-65-7) + Prenyltrimethylsilane (18293-99-7) + trimethyl-(3-methyl-but-3-enyl)-silane (18294-00-3) + 3-Methyl-1-butene (563-45-1)

Guidance literature:

In ethanol; at 45 ℃; Rate constant; other solvents;

DOI:10.1246/bcsj.72.741

Reference yield:

4-(trimethylsilyl)-2-chloro-2-methylbutane (18279-95-3) + trifluoroethanol-d3 (77253-67-9) → Prenyltrimethylsilane (18293-99-7) + trimethyl-(3-methyl-but-3-enyl)-silane (18294-00-3) + C8H19(2)HOSi + C10H19(2)H2F3OSi

Guidance literature:

With 2,6-dimethylpyridine; In water-d2; at 25 ℃; Further Variations:; Reaction partners; Product distribution;

DOI:10.1002/(SICI)1099-1395(199907)12:7<564::AID-POC164>3.0.CO;2-2

Reference yield:

chloro-trimethyl-silane (75-77-4) + 1,1-dibromo-2,2-dimethylcyclopropane (32264-50-9) → Prenyltrimethylsilane (18293-99-7) + trimethyl-(3-methyl-but-3-enyl)-silane (18294-00-3) + 1,1-bis(trimethylsilyl)-3-methyl-2-butene (73400-18-7) + 1,1-bis(trimethylsilyl)-3-methyl-3-butene

Guidance literature:

With magnesium; In tetrahydrofuran; for 4h; Mechanism; Ambient temperature; other gem-dibromocyclopropanes;

DOI:10.1016/S0022-328X(00)90528-X

upstream raw materials:

chloro-trimethyl-silane

1,1-dibromo-2,2-dimethylcyclopropane

4-(trimethylsilyl)-2-chloro-2-methylbutane

trifluoroethanol-d₃