1,3,2-Dioxaborinane, 5,5-dimethyl-2-[4-[(trimethylsilyl)ethynyl]phenyl]-

Base Information

Chemical Name:1,3,2-Dioxaborinane, 5,5-dimethyl-2-[4-[(trimethylsilyl)ethynyl]phenyl]-
CAS No.:183677-72-7
Molecular Formula:C16H23BO2Si
Molecular Weight:286.254
Hs Code.:
DSSTox Substance ID:DTXSID40468923
Nikkaji Number:J2.295.132G
Wikidata:Q82296425
Mol file:183677-72-7.mol

Synonyms:1,3,2-Dioxaborinane, 5,5-dimethyl-2-[4-[(trimethylsilyl)ethynyl]phenyl]-;183677-72-7;DTXSID40468923

Suppliers and Price of 1,3,2-Dioxaborinane, 5,5-dimethyl-2-[4-[(trimethylsilyl)ethynyl]phenyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 1,3,2-Dioxaborinane, 5,5-dimethyl-2-[4-[(trimethylsilyl)ethynyl]phenyl]-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:286.1560367
Heavy Atom Count:20
Complexity:384

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OCC(CO1)(C)C)C2=CC=C(C=C2)C#C[Si](C)(C)C

Technology Process of 1,3,2-Dioxaborinane, 5,5-dimethyl-2-[4-[(trimethylsilyl)ethynyl]phenyl]-

There total 7 articles about 1,3,2-Dioxaborinane, 5,5-dimethyl-2-[4-[(trimethylsilyl)ethynyl]phenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1066-54-2
trimethylsilylacetylene

: 183677-71-6
2-(4-bromophenyl)-5,5-dimethyl-1,3,2-dioxaborinane

: 183677-72-7
2,2-dimethylpropane-1,3-diyl [4-(trimethylsilylethynyl)phenyl] boronate

Guidance literature:: With copper(l) iodide; dimethyl amine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride; In N,N-dimethyl-formamide; at 120 ℃; for 0.333333h; microwave irradiation;
DOI:10.1016/j.tet.2007.04.035

Reference yield: 98.0%

: 1066-54-2
trimethylsilylacetylene

: 183677-71-6
2-(4-bromophenyl)-5,5-dimethyl-1,3,2-dioxaborinane

: 183677-72-7
2,2-dimethylpropane-1,3-diyl [4-(trimethylsilylethynyl)phenyl] boronate

: 630127-51-4
4-[(trimethylsilyl)ethynyl]phenyl boronic acid

Guidance literature:: With copper(l) iodide; diethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride; In N,N-dimethyl-formamide; at 120 ℃; for 0.416667h; microwave irradiation;
DOI:10.1016/j.tetlet.2006.02.012

Reference yield:

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 183677-72-7
2,2-dimethylpropane-1,3-diyl [4-(trimethylsilylethynyl)phenyl] boronate

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / toluene / 1 h / Heating

2: 98 percent / triphenylphosphine; diethylamine; CuI / PdCl₂(PPh₃)2 / dimethylformamide / 0.42 h / 120 °C / microwave irradiation

With copper(l) iodide; diethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride; In N,N-dimethyl-formamide; toluene; 2: Sonogashira reacion;
DOI:10.1016/j.tetlet.2006.02.012