Tris(4-fluorophenyl)phosphine sulfide

Base Information

• Chemical Name: Tris(4-fluorophenyl)phosphine sulfide
• CAS No.: 18437-80-4
• Molecular Formula: C18H12F3PS
• Molecular Weight: 348.328
• Mol file: 18437-80-4.mol

Synonyms:

Chemical Property of Tris(4-fluorophenyl)phosphine sulfide

Chemical Property:

• PSA: 0.00000
• LogP: 0.00000

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Tris(4-fluorophenyl)phosphine sulfide

There total 9 articles about Tris(4-fluorophenyl)phosphine sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphenyl trisulfide (20057-88-9) + P(p-C6H4F)3 (18437-78-0) → tris(4-fluorophenyl)phosphine sulfide (18437-80-4) + diphenyldisulfane (882-33-7)

Guidance literature:

In ⁽²⁾H₈-toluene; toluene; at 25 ℃; Rate constant;

Reference yield:

P(p-C6H4F)3 (18437-78-0) → tris(4-fluorophenyl)phosphine sulfide (18437-80-4)

Guidance literature:

With sulfur; In toluene; at 25 ℃; Rate constant; Mechanism;

Reference yield:

fluorobenzene (462-06-6) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → diphenyl(p-fluorophenyl)phosphine sulfide (18437-76-8) + Bis-(4-fluorphenyl)-phenyl-phosphansulfid (54300-40-2) + tris(4-fluorophenyl)phosphine sulfide (18437-80-4)

Guidance literature:

With trichlorophosphate; aluminium trichloride; Yield given. Multistep reaction. Yields of byproduct given; 1.) room temperature to 100 deg C, 2 h, 100 deg C, 4 h; 2.) 16 h;

upstream raw materials:

fluorobenzene

biphenyl

toluene

diphenyl trisulfide

Refernces

• 1、 Hanusek, Jiri,Russell, Mark A.,Laws, Andrew P.,Jansa, Petr,Atherton, John H.,Fettes, Kevin,Page, Michael I.. "Mechanism of the sulfurisation of phosphines and phosphites using 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride)". . p. 478 - 484. Retrieved 2008/03/27.
• 2、 Weiss, Erwin,Kleiner, Hans-Jerg. "ARYLIERUNG VON THIOPHOSPHORCHLORIDEN IN GEGENWART VON ALUMINIUM CHLORID". . p. 39 - 46. Retrieved 2007/10/02.