4-(2-Acetoxyacetyl)-1,2-phenylene diacetate

Base Information

• Chemical Name: 4-(2-Acetoxyacetyl)-1,2-phenylene diacetate
• CAS No.: 42529-03-3
• Molecular Formula: C14H14O7
• Molecular Weight: 294.261
• Hs Code.: 2918990090
• European Community (EC) Number: 255-871-1
• DSSTox Substance ID: DTXSID70195316
• Nikkaji Number: J309.941E
• Wikidata: Q83068205
• Mol file: 42529-03-3.mol

Synonyms:4-(2-Acetoxyacetyl)-1,2-phenylene diacetate;42529-03-3;EINECS 255-871-1;[2-(3,4-diacetyloxyphenyl)-2-oxoethyl] acetate;DTXSID70195316;2-(Acetyloxy)-1-[3,4-bis(acetyloxy)phenyl]ethanone;Ethanone, 2-(acetyloxy)-1-(3,4-bis(acetyloxy)phenyl)-

Chemical Property of 4-(2-Acetoxyacetyl)-1,2-phenylene diacetate

Chemical Property:

• Vapor Pressure: 7.66E-08mmHg at 25°C
• Boiling Point: 437.1°Cat760mmHg
• Flash Point: 194.7°C
• PSA: 95.97000
• Density: 1.264g/cm³
• LogP: 1.28300
• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 8
• Exact Mass: 294.07395278
• Heavy Atom Count: 21
• Complexity: 429

Purity/Quality:

98%Min ^*data from raw suppliers

4-(2-ACETOXYACETYL)-1,2-PHENYLENE DIACETATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)OCC(=O)C1=CC(=C(C=C1)OC(=O)C)OC(=O)C

Technology Process of 4-(2-Acetoxyacetyl)-1,2-phenylene diacetate

There total 4 articles about 4-(2-Acetoxyacetyl)-1,2-phenylene diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

2,4’-diacetoxyacetophenone (42528-99-4) + acetic anhydride (108-24-7) → 2,3’,4’-triacetoxyacetophenone (42529-03-3)

Guidance literature:

With 2-chloro-3',4'-dihydroxyacetophenone; potassium acetate; at 100 ℃;

DOI:10.1002/chem.201601564

Reference yield:

→ 2,3’,4’-triacetoxyacetophenone (42529-03-3)

Guidance literature:

With acetic acid; at 65 - 70 ℃;

Reference yield:

2-chloro-3',4'-dihydroxyacetophenone (99-40-1) + acetic anhydride (108-24-7) → 2,3’,4’-triacetoxyacetophenone (42529-03-3)

Guidance literature:

With potassium acetate;

upstream raw materials:

2-chloro-3',4'-dihydroxyacetophenone

acetic anhydride

potassium acetate

2-chloro-3′,4′-dihydroxyacetophenone

Downstream raw materials:

2-(3,4-dihydroxy-phenyl)-3,7,8-trihydroxy-chromenylium; chloride

fisetinidin chloride

6-hydroxycyanidin

(+/-)-2r-(3,4-dihydroxy-phenyl)-chroman-3c,7-diol