5-Ethenyl-6-(β-D-glucopyranosyloxy)-4,4a,5,6-tetrahydro-3-methoxy-1H,3H-pyrano[3,4-c]pyran-1-one

Base Information

Chemical Name:5-Ethenyl-6-(β-D-glucopyranosyloxy)-4,4a,5,6-tetrahydro-3-methoxy-1H,3H-pyrano[3,4-c]pyran-1-one
CAS No.:60077-47-6
Molecular Formula:C17H24O10
Molecular Weight:388.37
Hs Code.:
Mol file:60077-47-6.mol

Synonyms:secoiridoid β-D-glucopyranoside;vogeloside;epi-vogeloside;

Suppliers and Price of 5-Ethenyl-6-(β-D-glucopyranosyloxy)-4,4a,5,6-tetrahydro-3-methoxy-1H,3H-pyrano[3,4-c]pyran-1-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 4 raw suppliers

Chemical Property of 5-Ethenyl-6-(β-D-glucopyranosyloxy)-4,4a,5,6-tetrahydro-3-methoxy-1H,3H-pyrano[3,4-c]pyran-1-one

Chemical Property:

Boiling Point:640.2±55.0 °C(Predicted)
PKA:12.79±0.70(Predicted)
PSA：144.14000
Density:1.47±0.1 g/cm3(Predicted)
LogP:-1.61910

Purity/Quality:: Analysis control,97.0% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 5-Ethenyl-6-(β-D-glucopyranosyloxy)-4,4a,5,6-tetrahydro-3-methoxy-1H,3H-pyrano[3,4-c]pyran-1-one

There total 7 articles about 5-Ethenyl-6-(β-D-glucopyranosyloxy)-4,4a,5,6-tetrahydro-3-methoxy-1H,3H-pyrano[3,4-c]pyran-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 19351-63-4
secologanin

: 60077-47-6,118627-52-4
(4aS,5R,6S)-3-Methoxy-6-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-5-vinyl-4,4a,5,6-tetrahydro-3H-pyrano[3,4-c]pyran-1-one

Guidance literature:: Multi-step reaction with 4 steps

1: 94 percent / acidic ion exchange resin IR 120, Na₂SO₄ / acetonitrile / 24 h / 5 °C

2: 91 percent / pyridine / 24 h / 20 °C

3: 95 percent / 15 percent H₂SO₄/silica gel

With acidic ion exchange resin IR 120; sulfuric acid; silica gel; sodium sulfate; In pyridine; acetonitrile;

Reference yield:

: 79409-45-3
Methyl (2S,3R,4S)-4-(1,3-Dioxolan-2-ylmethyl)-2-(β-D-glucopyranosyloxy)-3,4-dihydro-3-vinyl-2H-pyran-5-carboxylate

: 60077-47-6,118627-52-4
(4aS,5R,6S)-3-Methoxy-6-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-5-vinyl-4,4a,5,6-tetrahydro-3H-pyrano[3,4-c]pyran-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / pyridine / 24 h / 20 °C

2: 95 percent / 15 percent H₂SO₄/silica gel

With sulfuric acid; silica gel; In pyridine;