2,2',6,6'-Tetrachlorodibenzylether

Base Information

• Chemical Name: 2,2',6,6'-Tetrachlorodibenzylether
• CAS No.: 73927-56-7
• Molecular Formula: C14H10 Cl4 O
• Molecular Weight: 336.045
• Mol file: 73927-56-7.mol

Synonyms:Bis(2,6-dichlorobenzyl) ether;2,6-DICHLOROBENZYL ETHER

Chemical Property of 2,2',6,6'-Tetrachlorodibenzylether

Chemical Property:

• Boiling Point: 397.9oC at 760 mmHg
• Flash Point: 139.7oC
• PSA: 9.23000
• Density: 1.417g/cm3
• LogP: 6.01700

Purity/Quality:

98%Min ^*data from raw suppliers

2,6-DICHLOROBENZYL ETHER Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2',6,6'-Tetrachlorodibenzylether

There total 3 articles about 2,2',6,6'-Tetrachlorodibenzylether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(2,6-Dichloro-phenyl)-methanol anion + 2,6-Dichlorobenzyl bromide (20443-98-5) → 2,6-dichlorobenzyl ether (73927-56-7)

Guidance literature:

DOI:10.1021/jo00001a050

Reference yield:

Dimethylphenylsilane (766-77-8) + 2,6-dichlorobenzaldehyde (83-38-5) → 2,6-dichlorobenzyl alcohol (15258-73-8) + C15H16Cl2OSi + 2,6-dichlorobenzyl ether (73927-56-7)

Guidance literature:

With dioxo-molybdenum supported on activated carbon; In 1,1,2,2-tetrachloroethane; at 100 ℃; for 24h; chemoselective reaction;

DOI:10.1039/c7cy00336f

Reference yield:

1,3-Dichloro-2-chloromethyl-benzene (2014-83-7) → 2,6-dichlorobenzyl ether (73927-56-7)

Guidance literature:

In NaH; ethyl acetate; N,N-dimethyl-formamide;

upstream raw materials:

2,6-Dichlorobenzyl bromide

1,3-Dichloro-2-chloromethyl-benzene

Dimethylphenylsilane

2,6-dichlorobenzaldehyde

Refernces

• 1、 Lai, Yee-Hing,Tan, Chin-Wee. "Synthesis and Conformational Study of 9,18-(Ethylenedioxy)-2,11-dithiametacyclophane: The Propelling Behavior of the Three Bridges in a (1,2,3)Cyclophane". . p. 264 - 267. Retrieved 2007/10/02.