Hydroperoxide, (1R)-1-phenylpropyl

Base Information

• Chemical Name: Hydroperoxide, (1R)-1-phenylpropyl
• CAS No.: 190506-77-5
• Molecular Formula: C9H12O2
• Molecular Weight: 152.193
• Mol file: 190506-77-5.mol

Synonyms:

Chemical Property of Hydroperoxide, (1R)-1-phenylpropyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Hydroperoxide, (1R)-1-phenylpropyl

There total 3 articles about Hydroperoxide, (1R)-1-phenylpropyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(+/-)-1-phenyl-propyl hydroperoxide (58687-91-5) → (R)-1-phenyl-1-propanol (1565-74-8) + (S)-1-phenyl-1-propanol (613-87-6) + (S)-1-phenyl-propyl hydroperoxide (164200-13-9) + (R)-1-phenyl-propyl hydroperoxide (190506-77-5) + 1-phenyl-propan-1-one (93-55-0)

Guidance literature:

With Coprinus peroxidase (CiP); 2-methoxy-phenol; In water; at 72 ℃; for 20h; Product distribution; phosphate buffer pH 7.0; enzyme-catalyzed kinetic resolution of chiral hydroperoxides in the presence and absence of guaiacol; selectivity; enantiomeric excess; CiP-catalyzed disproportionation; radical formation; mechanism; CiP-catalyzed sulfoxidation;

DOI:10.1021/jo990201p

Reference yield:

(+/-)-1-phenyl-propyl hydroperoxide (58687-91-5) → (R)-1-phenyl-1-propanol (1565-74-8) + (S)-1-phenyl-1-propanol (613-87-6) + (S)-1-phenyl-propyl hydroperoxide (164200-13-9) + (R)-1-phenyl-propyl hydroperoxide (190506-77-5)

Guidance literature:

With Paecilomyces sp; biotransformation by diverse microorganisms, conversion percent, enantiomeric excess;

DOI:10.1021/jo9818327

Reference yield:

(S)-1-phenyl-1-propanol (613-87-6) → (R)-1-phenyl-propyl hydroperoxide (190506-77-5)

Guidance literature:

With sulfuric acid; dihydrogen peroxide;

DOI:10.1039/jr9580004637

upstream raw materials:

(S)-1-phenyl-1-propanol

(+/-)-1-phenyl-propyl hydroperoxide

Downstream raw materials:

((R)-1-phenyl-propyl)-trityl peroxide

Refernces

• 1、 Driver, Tom G.,Harris, Jason R.,Woerpel. "Kinetic resolution of hydroperoxides with enantiopure phosphines: Preparation of enantioenriched tertiary hydroperoxides". . p. 3836 - 3837. Retrieved 2008/02/13.