Technology Process of (10-Bromoanthracen-9-YL)bis(2,4,6-trimethylphenyl)borane
There total 1 articles about (10-Bromoanthracen-9-YL)bis(2,4,6-trimethylphenyl)borane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
9,10-Dibromoanthracene;
With
n-butyllithium;
In
diethyl ether; hexane;
at 0 ℃;
for 0.5h;
dimesitylfluoroborane;
In
diethyl ether; hexane;
at 20 ℃;
for 14h;
Further stages.;
DOI:10.1021/ja994522u
- Guidance literature:
-
In
tetrahydrofuran; hexane;
(N2); Schlenk technique; BuLi/C6H14 added to stirred soln. of anthracenecompd./THF (3 equiv.) at -78°C; warmed to room temp.; stirred fo r 1 h; cooled to -78°C; soln. of Si compd./THF added dropwise; warmed to room temp.; stirred overnight; H2O and brine added; extd. (CH2Cl2); chromd. (silica gel, ethyl acetate/hexane, 1/20); elem. anal.;
DOI:10.1021/om049878f
- Guidance literature:
-
9-(dimesitylboryl)-10-bromoanthracene;
With
n-butyllithium;
In
diethyl ether; hexane;
at 0 ℃;
for 0.5h;
With
boron trifluoride diethyl etherate;
In
hexane;
at 20 ℃;
for 12h;
Further stages.;
DOI:10.1021/ja994522u
