5-(Chloromethyl)-1,2-dihydroacenaphthylene

Base Information

Chemical Name:5-(Chloromethyl)-1,2-dihydroacenaphthylene
CAS No.:62456-13-7
Molecular Formula:C13H11Cl
Molecular Weight:202.683
Hs Code.:2903999090
European Community (EC) Number:263-552-3
DSSTox Substance ID:DTXSID50978023
Nikkaji Number:J307.048D
Wikidata:Q82963371

Synonyms:5-(Chloromethyl)-1,2-dihydroacenaphthylene;62456-13-7;EINECS 263-552-3;5-chloromethylacenaphthene;DTXSID50978023;5-Chloromethyl-1,2-dihydroacenaphthylene

Suppliers and Price of 5-(Chloromethyl)-1,2-dihydroacenaphthylene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 5-(Chloromethyl)-1,2-dihydroacenaphthylene

Chemical Property:

Vapor Pressure:3.57E-05mmHg at 25°C
Boiling Point:364.3°Cat760mmHg
Flash Point:165.5°C
PSA：0.00000
Density:1.246g/cm³
LogP:3.67720
XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:202.0549280
Heavy Atom Count:14
Complexity:213

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2=CC=C(C3=CC=CC1=C23)CCl

Technology Process of 5-(Chloromethyl)-1,2-dihydroacenaphthylene

There total 4 articles about 5-(Chloromethyl)-1,2-dihydroacenaphthylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 50773-22-3
5-hydroxymethylacenaphthene

: 62456-13-7
5-chloromethylacenaphthene

Guidance literature:: With thionyl chloride; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1246/cl.200216

Reference yield:

: 91805-60-6
5-Bromoacenaphthene-6-carboxylic acid

: 5-bromo-6-chloromethylacenaphthene

: 62456-13-7
5-chloromethylacenaphthene

Guidance literature:: 5-Bromoacenaphthene-6-carboxylic acid; With lithium aluminium tetrahydride; In tetrahydrofuran; at 20 ℃; Inert atmosphere; Schlenk technique; Glovebox;

With hydrogenchloride; In tetrahydrofuran; water; at 0 ℃; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1039/c5dt00520e

Reference yield:

: 19190-91-1
5,6-dibromoacenaphthene

: 62456-13-7
5-chloromethylacenaphthene

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; cyclohexane / 0.33 h / -78 °C / Inert atmosphere; Schlenk technique; Glovebox

1.2: -78 - 20 °C / Inert atmosphere; Schlenk technique; Glovebox

1.3: pH 6 / Inert atmosphere; Schlenk technique; Glovebox

2.1: lithium aluminium tetrahydride / tetrahydrofuran / 20 °C / Inert atmosphere; Schlenk technique; Glovebox

2.2: 0 °C / Inert atmosphere; Schlenk technique; Glovebox

With lithium aluminium tetrahydride; n-butyllithium; In tetrahydrofuran; cyclohexane;
DOI:10.1039/c5dt00520e