19190-91-1

Usage

Uses

Used in Chemical Synthesis:
Acenaphthylene, 5,6-dibromo-1,2-dihydrois used as an intermediate in the synthesis of various chemical compounds. Its unique structure and bromine substitution make it a valuable building block for the development of new molecules with specific properties and applications.
Used in Pharmaceutical Industry:
Acenaphthylene, 5,6-dibromo-1,2-dihydromay be used as a starting material for the development of pharmaceutical compounds. Its chemical structure can be further modified to create potential drug candidates with specific therapeutic properties.
Used in Research and Development:
Due to its unique structure and properties, Acenaphthylene, 5,6-dibromo-1,2-dihydrocan be used in research and development for studying the effects of bromine substitution on the chemical and physical properties of polycyclic aromatic hydrocarbons. This knowledge can be applied to the design of new materials and compounds with tailored properties for various applications.

InChI:InChI=1/C12H8Br2/c13-9-5-3-7-1-2-8-4-6-10(14)12(9)11(7)8/h3-6H,1-2H2

Upstream product

• 2051-98-1 5-bromoacenaphthene 
• 83-32-9 acenaphthene 
• 43017-90-9 5-Amino-6-bromoacenaphthene 
• 4889-63-8 4‐bromo‐5‐nitroacenaphthene 

Downstream Products

• 13577-26-9 6,7-dibromo-1H,3H-naphtho<1,8-cd>pyran-1,3-dione 
• 83859-75-0 5,6-bis(p-formylphenyl)acenaphthene 
• 43017-99-8 5,6-dibromo-acenaphthene-1,2-dione 
• 1165939-99-0 C₃₈H₂₈O 
• 1165939-98-9 C₄₂H₃₆O 
• 1165939-97-8 C₅₄H₆₀O 
• 1165940-00-0 C₄₆H₄₄O 
• 1165940-01-1 C₃₈H₂₄F₄O 
• 1207426-56-9 acenapBr[P(OPh₂)2] 
• 1422960-18-6 5,6-bis[(2,6-dichlorophenyl)ethynyl]-1,2-dihydroacenaphthylene 
• 698386-69-5 cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)] 
• 1433220-91-7 cis-[platinum(II)(PPh₃)2(5,6-dihydroacenaphtho[5,6-cd][1,2]diselenolate)] 
• 1433220-92-8 cis-[platinum(II)(PPh₂Me)2(5,6-dihydroacenaphtho[5,6-cd][1,2]dithiolate)] 
• 1433220-93-9 cis-[platinum(II)(PPh₂Me)2(5,6-dihydroacenaphtho[5,6-cd][1,2]diselenolate)] 

Relevant academic research and scientific papers

Synthesis of Blue-Luminescent Seven-Membered Phosphorus Heterocycles

A facile synthetic procedure to prepare π-extended seven-membered phosphorus heterocycles, both symmetric and asymmetric, is reported. The prepared molecules present a persistent nonplanar framework and are soluble in a wide variety of solvents. The seven

The carbon skeleton of the belt region of fullerene C84 (D2)

The synthesis and structural characterization of the double-stranded carbon skeleton in the belt region of a C84 fullerene has been achieved. The synthetic methodology used is based on cyclic dimerization of diastereomeric AB-type monomers 18 b

PERI-BRIDGED NAPHTHALENES. 4. CHALCOGEN-BRIDGED ACENAPHTHYLENES

Three new electron donors, acenaphtho-1,2-dithiole (1), acenaphtho-1,2-diselenole (2), and acenaphtho-1,2-ditellurole (3), can be prepared in 28percent, 22percent, and 14percent yields respectively by reaction of the elemental chalcogens (S, Se, Te) with 5,6-dilithioacenaphthylene (4).Compound 4 is generated by treatment of 5,6-dibromoacenaphthylene (5), for which a convenient preparation is described, with n-butyllithium(2 equiv.) in THF at -78 deg C.

A Simple Molecular Design Strategy for Delayed Fluorescence toward 1000 nm

Harnessing the near-infrared (NIR) region of the electromagnetic spectrum is exceedingly important for photovoltaics, telecommunications, and the biomedical sciences. While thermally activated delayed fluorescent (TADF) materials have attracted much inter

Enhancement of Negative Photochromic Properties of Naphthalene-Bridged Phenoxyl-Imidazolyl Radical Complex

Negative photochromism has increased attention as a light-switch for functional materials. A development of fast photochromic molecules has been also expected because a rapid thermal back reaction within a millisecond time scale is useful for real-time switching. Herein, we synthesized the derivatives of the naphthalene-bridged phenoxyl-imidazolyl radical complex (Np?PIC) showing the negative photochromism to demonstrate the efficient strategy to increase the visible light sensitivity and to control the thermal back reaction rates. The distances of the C?C bond of the transient 2,4’-isomer shows good agreement with the thermodynamic stability, leading to the control of the thermal back reaction rate. We revealed the cyclic voltammetry and the DFT calculations are efficient to predict the characters of the HOMO and LUMO. The introduction of the electron-withdrawing dicyanoquinodimethane group is efficient to induce the photochromic reaction with increased visible-light sensitivity by the expansion of the π-conjugation. The results will give an important insight for the future development of fast-responsive negative photochromic molecules.

SYSTEMS AND METHODS FOR REGIOSELECTIVE CARBONYLATION OF 2,2-DISUBSTITUTED EPOXIDES FOR THE PRODUCTION OF ALPHA,ALPHA-DISUBSTITUTED BETA-LACTONES

Provided are methods of producing carbonyl compounds (e.g., carbonyl containing compounds) and catalysts for producing carbonyl compounds. Also provided are methods of making polymers from carbonyl compounds and polymers formed from carbonyl compounds. A method may produce carbonyl compounds, such as, for example α,α-disubstituted carbonyl compounds (e.g., α,α-disubstituted β-lactones). The polymers may be produced from α,α-disubstituted β-lactones, which may be produced by a method described herein.

Anomalous Halogen-Halogen Interaction Assists Radial Chromophoric Assembly

The design of highly efficient supramolecular architectures that mimic competent natural systems requires a comprehensive knowledge of noncovalent interactions. Halogen bonding is an excellent noncovalent interaction that forms halogen-halogen (X2) as well as trihalogen interacting synthons. Herein, we report the first observation of a symmetric radial assembly of chromophores (R3c space group) composed of a stable hexabromine interacting synthon (Br6) that further push the limits of our understanding on the nature, role, and potential of noncovalent halogen bonding. Contrary to the destabilization proposed for Type-I X2 interactions, Br6-synthon-possessing Type-I X2 interactions exhibit a stabilizing nature owing to the exchange-correlation component. The radial assembly of chromophores is further strengthened by intermolecular through-space charge transfer interaction. Br6-synthon-driven 3-fold symmetric radial assembly render a lattice structure that reminisces the chromophoric arrangement in the light harvesting system 2 of purple bacteria.

HETEROAROMATIC COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME

A heteroaromatic compound which can be used as the fluorescent guest material in the light emitting layer of the organic electroluminescence device is disclosed. The organic electroluminescence device employing the heteroaromatic compound of the present invention shows lower power consumption, higher efficiency, and longer half-life time than the existed organic electroluminescence devices.

Organic light-emitting material, application of organic light-emitting material and organic light-emitting device

The invention relates to an organic light-emitting material, application of the organic light-emitting material and an organic light-emitting device. The organic light-emitting material comprises a compound shown in the following general formula (1), which is shown in the description. In the general formula (1), Y1 and Y2 are respectively selected from one of hydrogen group and cyano group; X1 andX2 are respectively selected from one of CH or N; L1 is connected with one or two R1, L2 is connected with one or two R2, and L1 and L2 are respectively selected from hydrogen group or single bond, and/or aryl group/hetero aromatic ring with the annular atoms of 6 to 18; R1 and R2 are respectively selected from arylamine group with the annular atoms of 10 to 40. The organic light-emitting material adopts acenaphtho-pyrazine derivative as the structure general formula, and through modifying other different chemical groups, the organic light-emitting material has excellent luminescence characteristics, stable structure and higher colour purity, meanwhile, the preparation cost is relatively low.

Acenaphtho-pyrazine derivative and application thereof

The invention relates to an acenaphtho-pyrazine derivative and an application thereof. The acenaphtho-pyrazine derivative is a compound shown in a general formula (1). In the general formula (1), Y1 and Y2 are selected from one of a hydrogen group or a cyano group; L1 is linked with one or two R1s, L2 is linked with one or two R2s, the L1 and the L2 are selected from a hydrogen group or a single bond respectively and/or aryl/heteroaromatic ring with the ring atomic number of 6-18; R1 and R2 are selected from arylamine groups with the ring atomic number of 10-40. The acenaphtho-pyrazine derivative has excellent light emitting characteristics, stable structure and higher color purity through modification of other different chemical groups. Meanwhile, the preparation cost of the acenaphtho-pyrazine derivative is lower.