Carbamoperoxoic acid, [(4-methylphenyl)sulfonyl]-, 1,1-dimethylethyl ester

Base Information

• Chemical Name: Carbamoperoxoic acid, [(4-methylphenyl)sulfonyl]-, 1,1-dimethylethyl ester
• CAS No.: 19618-96-3
• Molecular Formula: C12H17NO5S
• Molecular Weight: 287.337
• Mol file: 19618-96-3.mol

Synonyms:

Chemical Property of Carbamoperoxoic acid, [(4-methylphenyl)sulfonyl]-, 1,1-dimethylethyl ester

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Carbamoperoxoic acid, [(4-methylphenyl)sulfonyl]-, 1,1-dimethylethyl ester

There total 2 articles about Carbamoperoxoic acid, [(4-methylphenyl)sulfonyl]-, 1,1-dimethylethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

tert.-butylhydroperoxide (75-91-2) + Tosyl isocyanate (4083-64-1) → N-(4-Methylphenylsulfonyl)-peroxycarbamidsaeure-tert.-butylester (19618-96-3)

Guidance literature:

for 8h; Ambient temperature;

DOI:10.1055/s-1997-1067

Reference yield:

→ N-(4-Methylphenylsulfonyl)-peroxycarbamidsaeure-tert.-butylester (19618-96-3)

Guidance literature:

Reference yield: 58.0%

N-(4-Methylphenylsulfonyl)-peroxycarbamidsaeure-tert.-butylester (19618-96-3) + cyclohexene (110-83-8) → N-cyclohex-2-enyl-4-methyl-benzenesulfonamide (57981-18-7)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); In dichloromethane; for 4h; Ambient temperature;

DOI:10.1055/s-1997-1067

upstream raw materials:

tert.-butylhydroperoxide

Tosyl isocyanate

Downstream raw materials:

4-methyl-N-(1,2,3,4-tetrahydronaphthalen-1-yl)benzenesulfonamide

N-(2,3-dihydro-1H-inden-1-yl)-4-methylbenzene sulfonamide

(±)-N-(cyclopent-2-en-1-yl)-4-methylbenzene-1-sulfonamide

N-cyclohex-2-enyl-4-methyl-benzenesulfonamide

Refernces