5-bromo-2-(trimethylstannyl)pyridine

Base Information

Chemical Name:5-bromo-2-(trimethylstannyl)pyridine
CAS No.:198985-48-7
Molecular Formula:C8H12BrNSn
Molecular Weight:320.804
Hs Code.:
Mol file:198985-48-7.mol

Synonyms:2-trimethylstannanyl-5-bromopyridine;5-bromo-2-trimethylstannylpyridine;5-bromo-2-trimethylstannyl pyridine;

Suppliers and Price of 5-bromo-2-(trimethylstannyl)pyridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 5-bromo-2-(trimethylstannyl)pyridine

Chemical Property:

PSA：12.89000
LogP:2.38930

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 5-bromo-2-(trimethylstannyl)pyridine

There total 2 articles about 5-bromo-2-(trimethylstannyl)pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 223463-13-6
2-iodo-5-bromopyridine

: 1066-45-1
trimethyltin(IV)chloride

: 198985-48-7
5-bromo-2-(trimethylstannyl)pyridine

Guidance literature:: With C₄H₉Li; In hexane; toluene; addn. of hexane soln. of butyllithium to toluene soln. of pyridine deriv. at -20°C, stirring at -78°C for 2 h, addn. of toluene soln. of tin compd., stirring for 1 h at -78°C, warming to room temp.; evapn., extn. (CH2Cl2), filtration, evapn., chromy. (alumina, diethyl ether), NMR and MS;
DOI:10.1039/b9nj00296k

Reference yield:

: 624-28-2
2,5-dibromopyridine

Pd₂ (dba)3: Pd₂ (dba)3

: 198985-48-7
5-bromo-2-(trimethylstannyl)pyridine

Guidance literature:: With hexamethyldistannane; triphenylphosphine; In 1,4-dioxane;

Reference yield: 68.0%

: 223463-13-6
2-iodo-5-bromopyridine

: 198985-48-7
5-bromo-2-(trimethylstannyl)pyridine

: 15862-18-7
5,5'-dibromo-2,2'-dipyridyl

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; for 20h; Inert atmosphere; Reflux;
DOI:10.1002/anie.200903311