Silane, chlorotris(pentafluorophenyl)-

Base Information

• Chemical Name: Silane, chlorotris(pentafluorophenyl)-
• CAS No.: 20160-39-8
• Molecular Formula: C18ClF15Si
• Molecular Weight: 564.713
• DSSTox Substance ID: DTXSID10464614
• Wikidata: Q82290012
• Mol file: 20160-39-8.mol

Synonyms:Silane, chlorotris(pentafluorophenyl)-;20160-39-8;SCHEMBL3129507;Tris(pentafluorphenyl)chlorsilan;DTXSID10464614

Chemical Property of Silane, chlorotris(pentafluorophenyl)-

Chemical Property:

• Boiling Point: 359.7±42.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.73±0.1 g/cm3(Predicted)
• LogP: 4.97880
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 15
• Rotatable Bond Count: 3
• Exact Mass: 563.9218267
• Heavy Atom Count: 35
• Complexity: 612

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(=C(C(=C(C(=C1F)F)[Si](C2=C(C(=C(C(=C2F)F)F)F)F)(C3=C(C(=C(C(=C3F)F)F)F)F)Cl)F)F)F

Technology Process of Silane, chlorotris(pentafluorophenyl)-

There total 13 articles about Silane, chlorotris(pentafluorophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

tris(pentafluorophenyl)silane (20160-40-1) + chlorine (7782-50-5) → tris-(pentafluoro phenyl) chloro silane (20160-39-8)

Guidance literature:

In further solvent(s); introduction of Cl2 into a solution of (C6F5)3SiH in tetrachloro ethane at 140°C, 6 hours;;

DOI:10.1007/BF00904310

Reference yield: 82.0%

tri-(pentafluoro phenyl) phenyl silane (17067-71-9) → tris-(pentafluoro phenyl) chloro silane (20160-39-8)

Guidance literature:

With aluminum tri-bromide; In dichloromethane; for 0.916667h; Ambient temperature;

DOI:10.1016/S0022-328X(98)00720-7

Reference yield: 59.1%

bis-{tris-(pentafluoro phenyl) silyl} mercury (30431-03-9) + mercury dichloride → tris-(pentafluoro phenyl) chloro silane (20160-39-8)

Guidance literature:

In tetrahydrofuran; reaction at 100°C, 18 hours;;

upstream raw materials:

tri-(pentafluoro phenyl) phenyl silane

bromopentafluorobenzene

tri-(pentafluoro phenyl) dimethylamino silane

acetyl chloride

Downstream raw materials:

1-phenyl-1-[tris(pentafluorophenyl)silyloxy]ethylene

hexakis-(pentafluoro phenyl) disilane

tris-(pentafluoro phenyl) silanol

β-(tris-(pentafluoro phenyl) silyl) styrol

Refernces