Benzenamine, 2-[(trimethylsilyl)ethynyl]-N-(triphenylphosphoranylidene)-

Base Information

Chemical Name:Benzenamine, 2-[(trimethylsilyl)ethynyl]-N-(triphenylphosphoranylidene)-
CAS No.:207278-64-6
Molecular Formula:C29H28NPSi
Molecular Weight:449.607
Hs Code.:
DSSTox Substance ID:DTXSID90455247
Wikidata:Q82277161

Synonyms:Benzenamine, 2-[(trimethylsilyl)ethynyl]-N-(triphenylphosphoranylidene)-;207278-64-6;DTXSID90455247

Suppliers and Price of Benzenamine, 2-[(trimethylsilyl)ethynyl]-N-(triphenylphosphoranylidene)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzenamine, 2-[(trimethylsilyl)ethynyl]-N-(triphenylphosphoranylidene)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:6
Exact Mass:449.17286343
Heavy Atom Count:32
Complexity:652

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C[Si](C)(C)C#CC1=CC=CC=C1N=P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Benzenamine, 2-[(trimethylsilyl)ethynyl]-N-(triphenylphosphoranylidene)-

There total 5 articles about Benzenamine, 2-[(trimethylsilyl)ethynyl]-N-(triphenylphosphoranylidene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 103529-16-4
2-[(trimethylsilyl)ethynyl]aniline

: 603-35-0
triphenylphosphine

: 207278-64-6
C₂₉H₂₈NPSi

Guidance literature:: With triethylamine; In dichloromethane; hexachloroethane; at 20 ℃; for 6h;
DOI:10.1039/c4ob00825a

Reference yield: 74.0%

: 103529-16-4
2-[(trimethylsilyl)ethynyl]aniline

: 1034-39-5
dibromotriphenylphosphorane

: 207278-64-6
C₂₉H₂₈NPSi

Guidance literature:: With triethylamine;
DOI:10.1021/jo9804285

Reference yield:

: 615-43-0
2-iodophenylamine

: 207278-64-6
C₂₉H₂₈NPSi

Guidance literature:: Multi-step reaction with 3 steps

1.1: NaNO₂; aq. HCl / 5 - 10 °C

1.2: 84 percent / NaN₃ / H₂O / 2 h / 5 °C

2.1: 99 percent / CuI; Et₃N / PdCl₂(PPh₃)2 / CH₂Cl₂ / 1 h / 20 °C

3.1: benzene / 1.5 h / 20 °C

With hydrogenchloride; copper(l) iodide; triethylamine; sodium nitrite; bis-triphenylphosphine-palladium(II) chloride; In dichloromethane; benzene; 2.1: Heck coupling reaction / 3.1: Staudinger reaction;
DOI:10.3987/COM-03-9726