Plumbane, tris(acetyloxy)phenyl-

Base Information

• Chemical Name: Plumbane, tris(acetyloxy)phenyl-
• CAS No.: 3076-54-8
• Molecular Formula: C12H14 O6 Pb
• Molecular Weight: 461.44
• UNII: 5CP8QP5VKD
• DSSTox Substance ID: DTXSID70184780
• NSC Number: 202893,102518
• Wikidata: Q83055720
• Mol file: 3076-54-8.mol

Synonyms:Plumbane, tris(acetyloxy)phenyl-;3076-54-8;NSC-102518;NSC-202893;[diacetyloxy(phenyl)plumbyl] acetate;phenyllead triacetate;NSC 102518;NSC 202893;Phenyltriacetoxyplumbane;Lead, triacetoxyphenyl-;5CP8QP5VKD;Plumbane, triacetoxyphenyl-;Tris(acetyloxy)phenylplumbane;Plumbane, tri(acetoxy)phenyl-;DTXSID70184780;NSC102518;NSC202893

Chemical Property of Plumbane, tris(acetyloxy)phenyl-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 7
• Exact Mass: 462.05569
• Heavy Atom Count: 19
• Complexity: 320

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)O[Pb](C1=CC=CC=C1)(OC(=O)C)OC(=O)C

Technology Process of Plumbane, tris(acetyloxy)phenyl-

There total 9 articles about Plumbane, tris(acetyloxy)phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

lead(IV) tetraacetate (546-67-8) + phenylboronic acid (98-80-6) → phenyllead(IV) triacetate (3076-54-8) + diphenyllead(IV) diacetate (6928-68-3)

Guidance literature:

In chloroform-d1; 40°C; not isolated; (1)H-NMR spectroscopy;

Reference yield: 75.0%

lead(IV) tetraacetate + tributylphenylstannane (960-16-7) → phenyllead(IV) triacetate (3076-54-8)

Guidance literature:

With Hg(OCOCF₃)2; In chloroform; stirring Pb(OAc)4 with equimolar amt. of Sn-compd. and 0.05 equiv. Hg(OCOCF3)2 (60°C, 72 h); filtration, concn. (40°C, vac.), dissoln. in petroleum ether, crystn. (4°C, overnight), filtration, washing (petroleum ether), drying (vac.); elem. anal.;

DOI:10.1016/S0022-328X(96)06477-7

Reference yield: 69.0%

lead(IV) acetate + tributylphenylstannane (960-16-7) → phenyllead(IV) triacetate (3076-54-8)

Guidance literature:

mercury(II) trifluoroacetate; In chloroform; byproducts: Bu3SnOAc; stirred at 40°C for 24 h;; filtered through Celite; solvent removed; light petroleum added; ppt. washed with light petroleum; crystd. from CHCl3/light petroleum;;

upstream raw materials:

triphenylboroxine

lead(IV) tetraacetate

phenylboronic acid

bis(propan-2-yl) phenylboronate

Downstream raw materials:

2-phenyl-acrylic acid ethyl ester

4-hydroxy-6-methoxy-3-phenyl-1-benzopyran-2-one

styrene

2-phenyl-2,5-dihydrofuran