platinum(2+) bis[(carboxymethyl)azanide]

Base Information

• Chemical Name: platinum(2+) bis[(carboxymethyl)azanide]
• CAS No.: 15685-00-4
• Molecular Formula: C₄H₈N₂O₄Pt
• Molecular Weight: 343.199
• Mol file: 15685-00-4.mol

Synonyms:Platinum,bis(glycinato)-, trans- (8CI); Platinum, bis(glycinato-N,O)-, (SP-4-1)-; NSC308291; trans-Bis(glycinato)platinum

Chemical Property of platinum(2+) bis[(carboxymethyl)azanide]

Chemical Property:

• Vapor Pressure: 0.0123mmHg at 25°C
• Boiling Point: 240.9°Cat760mmHg
• Flash Point: 99.5°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of platinum(2+) bis[(carboxymethyl)azanide]

There total 23 articles about platinum(2+) bis[(carboxymethyl)azanide] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + glycine (56-40-6,18875-39-3,25718-94-9) → trans-Bis(glycinato)platin(II) (15685-00-4) + cis-Pt(glycinate)2 (14281-82-4)

Guidance literature:

With alkali; In not given; formation on heating of K2(PtCl4) with glycine; alkaline soln.;; trans-:cis-compound = 1:5;;

Reference yield:

Pt(H2O)4(2+) (60911-98-0) + glycine (56-40-6,18875-39-3,25718-94-9) → trans-Bis(glycinato)platin(II) (15685-00-4) + cis-Pt(glycinate)2 (14281-82-4)

Guidance literature:

With sodium hydroxide; In water; NaOH soln. was added to equimolar soln. of Pt-complex and glycine to maintained the pH at 3-4 for several hours, insol. ppt. was formed; detected by IR spectra;

DOI:10.1021/ic00199a008

Reference yield:

{Pt(glH)2gl2} → trans-Bis(glycinato)platin(II) (15685-00-4) + cis-Pt(glycinate)2 (14281-82-4)

Guidance literature:

In water; formation on heating of (Pt(NH2CH2CO2H)2(NH2CH2CO2)2) in aq. soln.;;

upstream raw materials:

trans-trans-trans-dichlorobis(glycinato)platinum(IV)

potassium tetrachloroplatinate(II)

glycine

trans-[Pt(glycine)2Cl₂]

Downstream raw materials:

trans-[Pt(glycine)2Cl₂]

Refernces

• 1、 Ambach,Beck. "Metal complexes with biologically important ligands XXXVI [1]: Reaction of bis(α-aminoacidato) platinum(II) complexes with nitrosyl salts: Nitrosyl platinum complexes {(ON)Pt[NH2CR(R')C(O)O]2}+X- (X = BF4, PF6, SbF6)". . p. 288 - 291. Retrieved 2007/10/02.