Boroxin, tris(pentafluorophenyl)-

Base Information

• Chemical Name: Boroxin, tris(pentafluorophenyl)-
• CAS No.: 223440-98-0
• Molecular Formula: C18B3F15O3
• Molecular Weight: 581.60000
• Mol file: 223440-98-0.mol

Synonyms:

Chemical Property of Boroxin, tris(pentafluorophenyl)-

Chemical Property:

• PSA: 27.69000
• LogP: 3.32250

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Boroxin, tris(pentafluorophenyl)-

There total 4 articles about Boroxin, tris(pentafluorophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

pentafluorophenylboronic acid (1582-24-7) → 2,4,6-tris(pentafluorophenyl)-1,3,5,2,4,6-trioxatriborinane (223440-98-0)

Guidance literature:

With thionyl chloride; In diethyl ether; byproducts: SO2, HCl; excess of SOCl2 was added to Et2O soln. of B-compd., several min, room temp.; volatiles were removed from the ppt. in vac.;

DOI:10.1002/1521-3749(200213)628:13<2827::AID-ZAAC2827>3.0.CO;2-N

Reference yield: 97.0%

2-pentafluorophenyl-1,3,2-dioxaborolan-4,5-dione (34221-90-4) → 2,4,6-tris(pentafluorophenyl)-1,3,5,2,4,6-trioxatriborinane (223440-98-0)

Guidance literature:

In toluene; decompn. at 130°C, 1 h;

Reference yield: 20.0%

tris(pentafluorophenyl)borane monohydrate → 2,4,6-tris(pentafluorophenyl)-1,3,5,2,4,6-trioxatriborinane (223440-98-0)

Guidance literature:

With Si₂Cl₆; In benzene-d6; High Pressure; borane and Si2Cl6 dissolved in C6D6; heated to 453 K for 24 h in sealed NMRtube; cooled to room temp.;

DOI:10.1107/S0108270112016629

upstream raw materials:

pentafluorophenylboronic acid

2-pentafluorophenyl-1,3,2-dioxaborolan-4,5-dione

benzophenone

(tert-butylimino)-(pentafluorophenyl)borane

Downstream raw materials:

pentafluorophenylboronic acid