4'-(3,5-Di-tert-butylphenyl)-2,2':6',2''-terpyridine

Base Information

Chemical Name:4'-(3,5-Di-tert-butylphenyl)-2,2':6',2''-terpyridine
CAS No.:227948-34-7
Molecular Formula:C29H31N3
Molecular Weight:421.57700
Hs Code.:
DSSTox Substance ID:DTXSID10583258
Nikkaji Number:J1.138.963E
Wikidata:Q82474786
Mol file:227948-34-7.mol

Synonyms:227948-34-7;4'-(3,5-Di-tert-butylphenyl)-2,2':6',2''-terpyridine;4-(3,5-Ditert-butylphenyl)-2,6-dipyridin-2-ylpyridine;DTXSID10583258;CS-0203099;2~4~-(3,5-Di-tert-butylphenyl)-1~2~,2~2~:2~6~,3~2~-terpyridine

Suppliers and Price of 4'-(3,5-Di-tert-butylphenyl)-2,2':6',2''-terpyridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 4'-(3,5-Di-tert-butylphenyl)-2,2':6',2''-terpyridine

Chemical Property:

PSA：38.67000
LogP:7.46760
XLogP3:7.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:421.251798002
Heavy Atom Count:32
Complexity:540

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)C1=CC(=CC(=C1)C2=CC(=NC(=C2)C3=CC=CC=N3)C4=CC=CC=N4)C(C)(C)C

Technology Process of 4'-(3,5-Di-tert-butylphenyl)-2,2':6',2''-terpyridine

There total 1 articles about 4'-(3,5-Di-tert-butylphenyl)-2,2':6',2''-terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 1122-62-9
2-acetylpyridine

: 17610-00-3
3,5-Di-tert-butylbenzaldehyde

: 227948-34-7
4'-(3,5-di-tert-butylphenyl)-2,2':6',2-terpyridine

Guidance literature:: With acetamide; ammonium acetate; at 160 ℃; for 2h;
DOI:10.1021/ja9833669

Reference yield: 95.5%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 227948-34-7
4'-(3,5-di-tert-butylphenyl)-2,2':6',2-terpyridine

: 660860-77-5
Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

Guidance literature:: In ethanol; 4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine and one equiv. of RuCl3*3H2O dissolved in EtOH; soln. heated to reflux for 1 h; cooled; ppt. filtered; solid washed (EtOH, H2O, Et2O); dried (air);
DOI:10.1039/b310198c

Reference yield: 66.0%

: 17084-13-8
potassium hexafluorophosphate

: (H₂N₄(C₁₉H₂₃)3C₁₁H₆C₅H₂N(C₅H₄N)2IrCl₃)

: 227948-34-7
4'-(3,5-di-tert-butylphenyl)-2,2':6',2-terpyridine

: (H₂N₄(C₁₉H₂₃)3C₁₁H₆C₅H₂N(C₅H₄N)2IrC₁₄H₂₁C₅H₂N(NC₅H₄)2)⁽³⁺⁾*3PF₆^(1-)=(H₂N₄(C₁₉H₂₃)3C₁₁H₆C₁₅H₁₀N₃IrC₁₄H₂₁C₁₅H₁₀N₃)(PF₆)3

Guidance literature:: In ethylene glycol; porphyrine and Ar-tpy were heated in ethyle glycol under ar in the dark for 25 min, mixt. was cooled to room temp., aq. KPF6 was added; ppt. was filtered off and chromed on alumina and silica;
DOI:10.1021/ic010416t