trichloro(4'-(3,5-di-tert-butylphenyl)-2,2':6',6''-terpyridine)iridium(III)

Base Information

Chemical Name:trichloro(4'-(3,5-di-tert-butylphenyl)-2,2':6',6''-terpyridine)iridium(III)
CAS No.:227949-61-3
Molecular Formula:C₂₉H₃₁Cl₃IrN₃
Molecular Weight:720.164
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trichloro(4'-(3,5-di-tert-butylphenyl)-2,2':6',6''-terpyridine)iridium(III)

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Technology Process of trichloro(4'-(3,5-di-tert-butylphenyl)-2,2':6',6''-terpyridine)iridium(III)

There total 1 articles about trichloro(4'-(3,5-di-tert-butylphenyl)-2,2':6',6''-terpyridine)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: iridium(III) trichloride tetrahydrate

: 227948-34-7
4'-(3,5-di-tert-butylphenyl)-2,2':6',2-terpyridine

: 227949-61-3
trichloro(4'-(3,5-di-tert-butylphenyl)-2,2':6',6''-terpyridine)iridium(III)

Guidance literature:: In ethanol; dropwise addn. of IrCl3 soln., refluxing (dark, 3 h); evapn., dissolving (CH2Cl2), chromy. (Al2O3, hexane/ether, CH2Cl2/MeOH=99:1);
DOI:10.1021/ja9833669

Reference yield: 96.0%

: 17084-13-8
potassium hexafluorophosphate

: 227949-61-3
trichloro(4'-(3,5-di-tert-butylphenyl)-2,2':6',6''-terpyridine)iridium(III)

: 371960-90-6
(Au(N₄(C₅H₂C₆H₃(C₄H₉)2)3(C₅H₂C₆H₄C₅H₂N(C₅H₄N)2)))⁽¹⁺⁾*PF₆^(1-)=(Au(N₄(C₅H₂C₆H₃(C₄H₉)2)3(C₅H₂C₆H₄C₅H₂N(C₅H₄N)2)))PF₆

: (AuN₄(C₁₉H₂₃)3C₁₁H₆C₅H₂N(C₅H₄N)2IrC₁₄H₂₁C₅H₂N(NC₅H₄)2)⁽⁴⁺⁾*4PF₆^(1-)=(AuN₄(C₁₉H₂₃)3C₁₁H₆C₁₅H₁₀N₃IrC₁₄H₂₁C₁₅H₁₀N₃)(PF₆)4

Guidance literature:: In ethylene glycol; porphyrine and Ir(Ar-tpr)Cl3 were heated in ethylene glycol at 140°C under Ar in the dark for 3 h, solvent was evapd. under reduced pressure, residue was dissolved in acetone and ppt. by adn. KPF6; ppt. was filtered and chromed on silica;
DOI:10.1021/ic010416t

Reference yield: 85.0%

: 17084-13-8
potassium hexafluorophosphate

: 227949-61-3
trichloro(4'-(3,5-di-tert-butylphenyl)-2,2':6',6''-terpyridine)iridium(III)

: 178265-65-1
4′-(4-amino-phenyl)-2,2′:6′,2′′-terpyridine

: Ir((3,5-di-tert-butylphenyl)-2,2':6',2''-terpyridine)(p-anilino-2,2':6',2''-terpyridine)(PF₆)3

Guidance literature:: In water; ethylene glycol; other Radiation; Ir-complex and ligand were dissolved in ethylene glycol, sonicated, refluxed for 5 min under microwave irradiation, aq. KPF6 was added; filtered, chromd. on silica with MeCN/H2O/KNO3;
DOI:10.1021/ic0351038