Nickel, tetrakis(isocyanobenzene)-

Base Information

• Chemical Name: Nickel, tetrakis(isocyanobenzene)-
• CAS No.: 23411-45-2
• Molecular Formula: C28H20N4Ni
• Molecular Weight: 471.184
• Mol file: 23411-45-2.mol

Synonyms:

Chemical Property of Nickel, tetrakis(isocyanobenzene)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Nickel, tetrakis(isocyanobenzene)-

There total 12 articles about Nickel, tetrakis(isocyanobenzene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + phenyl isocyanate (1197040-29-1,931-54-4) → tetrakis(phenyl isocyanide)nickel(O) (23411-45-2)

Guidance literature:

In toluene; all manipulations under Ar atm.; soln. of isocyanide added to soln. of Ni compd. over period of 1 h at room temp.; concd., cooled to -10°C, after 24 h filtered; elem. anal.;

DOI:10.1515/znb-2004-0814

Reference yield: 66.0%

(CO)3NiC(CH3)2P(C6H5)3 (39045-51-7) + phenyl isocyanate (1197040-29-1,931-54-4) → tetrakis(phenyl isocyanide)nickel(O) (23411-45-2) + triphenylphosphine (603-35-0)

Guidance literature:

byproducts: CO; prepn. from (CO)3NiC(CH3)2P(C6H5)3 and 11-fold excess of C6H5NC;;

Reference yield: 56.5%

potassium hexacyanoniccolate (I) + phenyl isocyanate (1197040-29-1,931-54-4) → tetrakis(phenyl isocyanide)nickel(O) (23411-45-2)

Guidance literature:

In ammonia; react. in liq. NH3 at -33 - -40 °C;;

upstream raw materials:

benzonitrile

tetracarbonyl nickel

phenyl isocyanate

nickelocene