10-Undecenyl 2-broMoisobutyrate

Base Information

• Chemical Name: 10-Undecenyl 2-broMoisobutyrate
• CAS No.: 255727-66-3
• Molecular Formula: C15H27BrO2
• Molecular Weight: 319.27800
• Hs Code.: 2915900090
• Mol file: 255727-66-3.mol

Synonyms:undec-10-en-1-yl 2-bromo-2-methylpropanoate;10-undecen-1-yl 2-bromo-2-methylpropionate;Allyl-type (long chain) initiator;10-Undecenyl 2-bromoisobutyrate;

Chemical Property of 10-Undecenyl 2-broMoisobutyrate

Chemical Property:

• Refractive Index: n20/D1.450
• Boiling Point: 336.6±15.0 °C(Predicted)
• Flash Point: >110℃
• PSA: 26.30000
• Density: 1.080 g/mL at 25 °C
• LogP: 5.00990

Purity/Quality:

98%,99%, ^*data from raw suppliers

10-UNDECENYL 2-BROMOISOBUTYRATE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-36/37/38
• Safety Statements: 26-36/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-Undecenyl 2-broMoisobutyrate

There total 2 articles about 10-Undecenyl 2-broMoisobutyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2-bromoisobutyric acid bromide (20769-85-1) + 10-Undecen-1-ol (112-43-6) → undec-10-en-1-yl 2-bromo-2-methylpropanoate (255727-66-3)

Guidance literature:

With pyridine; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1002/pola.26468

Reference yield:

→ undec-10-en-1-yl 2-bromo-2-methylpropanoate (255727-66-3)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 4 - 20 ℃; for 18h; Inert atmosphere;

Reference yield: 79.0%

undec-10-en-1-yl 2-bromo-2-methylpropanoate (255727-66-3) → (11-(2-bromo-2-methyl)-propionyloxy)undecyltrichlorosilane (255727-67-4)

Guidance literature:

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; trichlorosilane; In 5,5-dimethyl-1,3-cyclohexadiene; at 20 ℃; for 4h; Schlenk technique; Inert atmosphere;

DOI:10.1002/anie.201805534

upstream raw materials:

2-bromoisobutyric acid bromide

10-Undecen-1-ol

Downstream raw materials:

(11-(2-bromo-2-methyl)-propionyloxy)undecyltrichlorosilane