N~1~,N~1~,N~4~,N~4~-Tetrakis(trimethylsilyl)benzene-1,4-diamine

Base Information

Chemical Name:N~1~,N~1~,N~4~,N~4~-Tetrakis(trimethylsilyl)benzene-1,4-diamine
CAS No.:25811-68-1
Molecular Formula:C18H40N2Si4
Molecular Weight:396.871
Hs Code.:2931900090
DSSTox Substance ID:DTXSID00572838
Nikkaji Number:J46.983A
Wikidata:Q63395944
Mol file:25811-68-1.mol

Synonyms:25811-68-1;DTXSID00572838;N~1~,N~1~,N~4~,N~4~-Tetrakis(trimethylsilyl)benzene-1,4-diamine;Q63395944;N,N,N',N'-TETRAKIS(TRIMETHYLSILYL)-',4-PHENYLENEDIAMINE

Suppliers and Price of N~1~,N~1~,N~4~,N~4~-Tetrakis(trimethylsilyl)benzene-1,4-diamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of N~1~,N~1~,N~4~,N~4~-Tetrakis(trimethylsilyl)benzene-1,4-diamine

Chemical Property:

PSA：6.48000
LogP:6.63900
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:396.22685542
Heavy Atom Count:24
Complexity:337

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)N(C1=CC=C(C=C1)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

Technology Process of N~1~,N~1~,N~4~,N~4~-Tetrakis(trimethylsilyl)benzene-1,4-diamine

There total 5 articles about N~1~,N~1~,N~4~,N~4~-Tetrakis(trimethylsilyl)benzene-1,4-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 589-87-7
1,4-bromoiodobenzene

: 4039-32-1
lithium hexamethyldisilazane

: 25811-68-1
N,N,N',N'-tetrakis(trimethylsilyl)-1,4-phenylenediamine

Guidance literature:: With chlorotris(triphenylphosphine)cobalt(I); bis[2-(diphenylphosphino)phenyl] ether; In toluene; at 100 ℃; for 12h;
DOI:10.1039/c4sc01257g

Reference yield:

: 106-50-3
1,4-phenylenediamine

: 25811-68-1
N,N,N',N'-tetrakis(trimethylsilyl)-1,4-phenylenediamine

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / NEt₃ / benzene / 3 h / Heating

2: 1.) 1.6M n-BuLi / 1.) benzene, n-hexane, reflux, 1 h, 2.) benzene, n-hexane, reflux, 24 h

With n-butyllithium; triethylamine; In benzene;

Reference yield:

: 106-37-6
1.4-dibromobenzene

: 4039-32-1
lithium hexamethyldisilazane

: 25811-68-1
N,N,N',N'-tetrakis(trimethylsilyl)-1,4-phenylenediamine

Guidance literature:: With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; at 20 ℃; for 20h; Further Variations:; Temperatures; reaction times; Product distribution;
DOI:10.1021/ol016333y