1,3,2-Diazaborolidin-2-amine, N,N,1,3-tetramethyl-

Base Information

• Chemical Name: 1,3,2-Diazaborolidin-2-amine, N,N,1,3-tetramethyl-
• CAS No.: 26944-84-3
• Molecular Formula: C6H16BN3
• Molecular Weight: 141.024
• Mol file: 26944-84-3.mol

Synonyms:

Chemical Property of 1,3,2-Diazaborolidin-2-amine, N,N,1,3-tetramethyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,2-Diazaborolidin-2-amine, N,N,1,3-tetramethyl-

There total 3 articles about 1,3,2-Diazaborolidin-2-amine, N,N,1,3-tetramethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

tris(dimethylamino)borane (4375-83-1) + N,N`-dimethylethylenediamine (110-70-3) → 1,3-dimethyl-2-dimethylaminodiazaborolane (26944-84-3) + dimethyl amine (124-40-3)

Guidance literature:

transamination, boiling the reactants under nitrogene in inert atmosphere, distn. of dimethylamine during the reaction; distn.;

DOI:10.1021/ic50086a063

Reference yield:

(CH3)2N2C2H4B(N2C3H3)N(CH3)2B(C2H5)2 → 1,3-dimethyl-2-dimethylaminodiazaborolane (26944-84-3) + 4,4,8,8-tetraethylpyrazabole (14695-69-3)

Guidance literature:

exothermic reaction;

DOI:10.1016/S0022-328X(00)82505-X

Reference yield:

B(N(CH3)CH2CH2N(CH3))(N2C3H3) (77172-65-7) + (dimethylamino)diethylborane (7397-47-9) → 1,3-dimethyl-2-dimethylaminodiazaborolane (26944-84-3) + 4,4,8,8-tetraethylpyrazabole (14695-69-3)

Guidance literature:

under a dry Ar atm.; exothermic reaction, then heated to reflux for 30 min, volaties removed at room temp. under vac.; residue recrystn. from n-hexane identified by spectroscopy;

DOI:10.1016/S0022-328X(00)82505-X

upstream raw materials:

tris(dimethylamino)borane

N,N`-dimethylethylenediamine

B(N(CH₃)CH₂CH₂N(CH₃))(N₂C₃H₃)

(dimethylamino)diethylborane

Downstream raw materials:

dimethylamine borane

C₂H₄N₂B(CH₃)2BH₃HN(CH₃)2BH₂

Refernces

• 1、 Niedenzu, Kurt,Busse, Paul J.,Miller, Clifford D.. "Boron-nitrogen compounds. XXXII. 2-Amino-1,3,2-diazaboracycloalkanes". . p. 977 - 978. Retrieved 2007/10/05.