Heptafluoroisopropyl iodide

Base Information

• Chemical Name: Heptafluoroisopropyl iodide
• CAS No.: 677-69-0
• Molecular Formula: C3F7I
• Molecular Weight: 295.926
• Hs Code.: 29037800
• European Community (EC) Number: 211-643-3
• UNII: DGX6HT3JF7
• DSSTox Substance ID: DTXSID5060982
• Nikkaji Number: J129.116E
• Wikidata: Q72481284
• Mol file: 677-69-0.mol

Synonyms:Heptafluoroisopropyl iodide;677-69-0;Heptafluoro-2-iodopropane;2-Iodoheptafluoropropane;Perfluoroisopropyl iodide;1,1,1,2,3,3,3-Heptafluoro-2-iodopropane;Propane, 1,1,1,2,3,3,3-heptafluoro-2-iodo-;2-Iodoperfluoropropane;C3F7I;Propane, heptafluoro-2-iodo-;EINECS 211-643-3;DGX6HT3JF7;MFCD00042089;Perfluoro-2-iodopropane;Isoheptafluoropropyliodide;UNII-DGX6HT3JF7;SCHEMBL699189;DTXSID5060982;Heptafluoro-2-iodopropane, 98%;AMY6815;BCP24414;FD2092;AKOS005063400;AS-59063;SY032179;LS-120820;CS-0108612;FT-0612071;H0629;EN300-42498;1,1,1,2,3,3,3-Heptafluoro-2-iodopropane #;A835880;1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl iodide

Chemical Property of Heptafluoroisopropyl iodide

Chemical Property:

• Appearance/Colour: clear colorless to yellowish liquid
• Vapor Pressure: 7.12 psi ( 20 °C)
• Melting Point: -58 °C
• Refractive Index: n20/D 1.329(lit.)
• Boiling Point: 40.8 °C at 760 mmHg
• Flash Point: 4.7 °C
• PSA: 0.00000
• Density: 2.189 g/cm³
• LogP: 3.21180
• Storage Temp.: Keep Cold
• Sensitive.: Light Sensitive
• Water Solubility.: insoluble
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 295.89329
• Heavy Atom Count: 11
• Complexity: 129

Purity/Quality:

98% ^*data from raw suppliers

2-Iodoheptafluoropropane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, Xi, T
• Hazard Codes: Xn,Xi,T
• Statements: 20-36/37/38
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Halogenated Aliphatics, Saturated
• Canonical SMILES: C(C(F)(F)F)(C(F)(F)F)(F)I
• Uses: Heptafluoro-2-iodopropane may be used in the preparation of perfluoropropyl magnesium bromide and perfluoropropyl magnesium iodide. It may be used as chain-transfer agent in telomerization reactions of:1,1-difluoroethylene and tetrafluoroethyleneCF3I, C2F5I and n-C3F7I with 1,1-difluoroethylenen-C3F7I with tetrafluoroethylene

Technology Process of Heptafluoroisopropyl iodide

There total 23 articles about Heptafluoroisopropyl iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → perfluoroisopropyl iodide (677-69-0)

Guidance literature:

With hydrogen fluoride; boron trifluoride; Iodine monochloride; at 50 ℃; for 18h;

DOI:10.1021/jo961271o

Reference yield:

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) + 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane (423-39-2) → perfluoroisopropyl iodide (677-69-0)

Guidance literature:

aluminum chlorofluoride;

Reference yield:

→ 1,1,1,2,3,3,3-Heptafluoropropane (431-89-0) + perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) + perfluoroisopropyl iodide (677-69-0)

Guidance literature:

at 80 - 160 ℃; under 0.5 Torr;

DOI:10.1021/jo970805y

upstream raw materials:

perfluoropropylene

iodotrifluoromethane

perfluoroisopropyl radical

1,1,1,2,3,3,3-Heptafluoro-2-(1,2,2,2-tetrafluoro-1-iodo-ethoxy)-propane

Downstream raw materials:

4-Butoxy-1,1,1,2-tetrafluoro-4-methoxy-2-trifluoromethyl-butane

1,1,1,2-tetrafluoro-2-(trifluoromethyl)-4-iodotetradecane

perfluoroisopropyl phenyl ketone

(E)-4,5,5,5-Tetrafluoro-4-trifluoromethyl-pent-2-en-1-ol

Refernces

• 1、 Lewandowski, Grzegorz,Meissner, Egbert,Milchert, Eugeniusz. "Synthesis of telogens and optimization of tetrafluoroethene telomerization process". . p. 337 - 344. Retrieved 2007/10/03.
• 2、 -. "Process for the preparation of fluoroolefins". . . Retrieved 2008/06/13.