Cyclopentanone O-methyl oxime

Base Information

• Chemical Name: Cyclopentanone O-methyl oxime
• CAS No.: 3376-37-2
• Molecular Formula: C6H11NO
• Molecular Weight: 113.15800
• Mol file: 3376-37-2.mol

Synonyms:Cyclopentanon-;Cyclopentanon-(O-methyl-oxim);Cyclopentanone O-methyl-oxime;Cyclopentanonoxim-O-methylaether;

Chemical Property of Cyclopentanone O-methyl oxime

Chemical Property:

• PSA: 21.59000
• LogP: 1.56280

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cyclopentanone O-methyl oxime

There total 2 articles about Cyclopentanone O-methyl oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + cyclopentanone (120-92-3) → cyclopentanone-(O-methyl oxime ) (3376-37-2)

Guidance literature:

With pyridine; hydroxylamine hydrochloride; at 20 ℃; Inert atmosphere;

DOI:10.1002/anie.201909151

Reference yield:

Cyclopentanone oxime (1192-28-5) → cyclopentanone-(O-methyl oxime ) (3376-37-2)

Guidance literature:

With dimethyl sulfate;

DOI:10.1051/epjap:2001142

Reference yield: 62.0%

cyclopentanone-(O-methyl oxime ) (3376-37-2) + 1-nitro-4-trifluoroacetoxy-benzene (658-78-6) → 3-(4-Nitrophenoxy)-3-trifluoromethyl-1,2,4-trioxaspiro<4.4>nonane

Guidance literature:

With ozone; In pentane; at 0 ℃;

upstream raw materials:

Cyclopentanone oxime

methanol

cyclopentanone

Refernces

• 1、 Behnke, Nicole Erin,Lovato, Kaitlyn,Yousufuddin, Muhammed,Kürti, László. "Titanium-Mediated Synthesis of Spirocyclic NH-Azetidines from Oxime Ethers". supporting information. p. 14219 - 14223. Retrieved 2019/09/06.