1-Methoxydodecane

Base Information

• Chemical Name: 1-Methoxydodecane
• CAS No.: 3482-63-1
• Molecular Formula: C13H28 O
• Molecular Weight: 200.365
• Hs Code.: 2909199090
• European Community (EC) Number: 222-465-0
• DSSTox Substance ID: DTXSID60188358
• Nikkaji Number: J60.919F
• Wikidata: Q83060165
• Mol file: 3482-63-1.mol

Synonyms:1-Methoxydodecane;Dodecane, 1-methoxy-;3482-63-1;EINECS 222-465-0;1-Methoxidedecane;dodecyl methyl ether;SCHEMBL91957;SCHEMBL7936579;DTXSID60188358;FT-0608013

Chemical Property of 1-Methoxydodecane

Chemical Property:

• Vapor Pressure: 0.0317mmHg at 25°C
• Refractive Index: 1.4172 (estimate)
• Boiling Point: 251.9°Cat760mmHg
• Flash Point: 92.8°C
• PSA: 9.23000
• Density: 0.803g/cm³
• LogP: 4.55370
• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 11
• Exact Mass: 200.214015512
• Heavy Atom Count: 14
• Complexity: 91.2

Purity/Quality:

99% ^*data from raw suppliers

1-METHOXYDODECANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCOC

Technology Process of 1-Methoxydodecane

There total 17 articles about 1-Methoxydodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

methanol (67-56-1) + n-dodecyl phenyl telluroxide hydrate (84988-08-9) → n-dodecyl methyl ether (3482-63-1)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; at 20 - 25 ℃; for 1h;

DOI:10.1016/S0040-4039(00)88338-0

Reference yield: 95.0%

methanol (67-56-1) + dodecyl phenyl telluroxide monohydrate (84988-08-9) → n-dodecyl methyl ether (3482-63-1)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; at 25 ℃; for 1h;

Reference yield: 92.0%

1-dodecyl alcohol (112-53-8) → n-dodecyl methyl ether (3482-63-1)

Guidance literature:

With tetrafluoroboric acid; In hexane; dichloromethane; at 0 ℃; for 30h;

DOI:10.1016/S0040-4039(00)97884-5

upstream raw materials:

methanol

Dodecanal

1-Iodododecane

dodecyl phenyl selenide

Downstream raw materials:

dodecyl trimethylsilyl ether

methylphenyltelluride

1-dodecyl alcohol

Refernces

• 1、 Miura, Katsukiyo,Inoue, Gen,Sasagawa, Hisashi,Kinoshita, Hidenori,Ichikawa, Junji,Hosomi, Akira. "Platinum-catalyzed nucleophilic addition of vinylsilanes at the β-position". supporting information; experimental part. p. 5066 - 5069. Retrieved 2009/12/28.
• 2、 Aoyama, Toyohiko,Shioiri, Takayuki. "TRIMETHYLSILYLDIAZOMETHANE: A CONVENIENT REAGENT FOR THE O-METHYLATION OF ALCOHOLS". . p. 5507 - 5508. Retrieved 2007/10/02.