2-Furancarbodithioic acid methyl ester

Base Information

• Chemical Name: 2-Furancarbodithioic acid methyl ester
• CAS No.: 35972-85-1
• Molecular Formula: C6H6OS2
• Molecular Weight: 158.24100
• Mol file: 35972-85-1.mol

Synonyms:2-Furancarbodithioic acid,methyl ester;furan-2-carbodithioic acid methyl ester;Methyl 2-furancarbodithioate;2-Furandithiocarbonsaeure-methylester;

Chemical Property of 2-Furancarbodithioic acid methyl ester

Chemical Property:

• PSA: 70.53000
• LogP: 2.31810

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Furancarbodithioic acid methyl ester

There total 3 articles about 2-Furancarbodithioic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

2-furoic acid methyl ester (611-13-2) → methyl furan-2-carbodithioate (35972-85-1) + O-methyl furan-2-carbothiono ester (76190-23-3)

Guidance literature:

With Lawessons reagent; In xylene; for 10h; Heating;

Reference yield:

furan (110-00-9) + carbon disulfide (75-15-0,12122-00-8) + methyl iodide (74-88-4) → methyl furan-2-carbodithioate (35972-85-1)

Guidance literature:

With n-butyllithium; lithium bromide; copper(I) bromide; Yield given. Multistep reaction; 1.) hexane and THF, 0 deg C; 2.) from 0 deg C to 15 deg C;

DOI:10.1016/0022-328X(87)85127-6

Reference yield:

→ methyl furan-2-carbodithioate (35972-85-1)

Guidance literature:

2-Furandithiocarbonsaeurecarboxymethylester, CH3SH;

DOI:10.1002/oms.1210060406

upstream raw materials:

2-furoic acid methyl ester

furan

carbon disulfide

methyl iodide

Downstream raw materials:

(Z)-4-[(furan-2-yl)(methylthio)methylene]-2-phenyloxazol-5(4H)-one

(E)-4-[(furan-2-yl)(methylthio)methylene]-2-phenyloxazol-5(4H)-one

2-(4-bromo-1,3-diphenyl-1H-pyrazol-5-yl)-3-(2-furanyl)-3-methylthio-2-propenenitrile

1,3-diphenyl-5-(2-furyl)-1H-thieno[3,2-c]pyrazole-6-carbonitrile